Table 1.
Compound | CAS | Formula | MW | RI | Rt [s] | Dt [a.u.] | Chamomile | ‘Xiaokuixiang’ | ‘Huangju’ | ‘Hangju’ |
---|---|---|---|---|---|---|---|---|---|---|
(E)-2-Hexenal dimer | C6728263 | C6H10O | 98.1 | 845 | 341.96 | 1.52 | 119.15 ± 13.38 | 75.51 ± 3.9 | 2584.61 ± 200.04 | 164.85 ± 17.54 |
(E)-2-Hexenal monomer | C6728263 | C6H10O | 98.1 | 845.9 | 343.05 | 1.19 | 266.3 ± 4.4 | 118.7 ± 13.32 | 1466.64 ± 58.49 | 460.29 ± 37.3 |
1,8-Cineole dimer | C470826 | C10H18O | 154.3 | 1039.4 | 668.17 | 1.73 | 2288.27 ± 95.94 | 1703.92 ± 33.27 | 10,356.01 ± 304.58 | 269.45 ± 17.21 |
1,8-Cineole monomer | C470826 | C10H18O | 154.3 | 1039.9 | 669.06 | 1.30 | 4666.11 ± 33.93 | 2808.24 ± 98.28 | 4684.26 ± 217.57 | 1709.26 ± 147.07 |
1-Menthol dimer | C2216515 | C10H20O | 156.3 | 1164.6 | 899.45 | 1.89 | 76.31 ± 8.05 | 104.58 ± 9.7 | 611.43 ± 44.5 | 95 ± 8.35 |
1-Menthol monomer | C2216515 | C10H20O | 156.3 | 1167.1 | 904.07 | 1.22 | 1523.09 ± 132.67 | 1832.42 ± 212.92 | 13,371.96 ± 646.6 | 3336.42 ± 842.92 |
1-Octen-3-one | C4312996 | C8H14O | 126.2 | 980.7 | 559.80 | 1.27 | 147.74 ± 10.47 | 457.74 ± 30.52 | 185.63 ± 11.63 | 132.28 ± 8.71 |
1-Propanol | C71238 | C3H8O | 60.1 | 567.8 | 133.48 | 1.11 | 277.14 ± 37.46 | 510.58 ± 137.29 | 285.27 ± 70.16 | 120.95 ± 13.73 |
2-Butanone dimer | C78933 | C4H8O | 72.1 | 598.6 | 148.07 | 1.25 | 66.32 ± 8.38 | 206.39 ± 16.58 | 91.84 ± 11.82 | 56.38 ± 2.7 |
2-Butanone monomer | C78933 | C4H8O | 72.1 | 600.2 | 148.81 | 1.06 | 225.59 ± 5.57 | 304.15 ± 9.95 | 256.77 ± 17.37 | 224.55 ± 3.13 |
2-Methyl butanol dimer | C137326 | C5H12O | 88.1 | 730.6 | 226.07 | 1.47 | 74.41 ± 43.88 | 377.13 ± 39.66 | 61.58 ± 6.67 | 24.73 ± 1.82 |
2-Methyl butanol monomer | C137326 | C5H12O | 88.1 | 732.1 | 227.38 | 1.22 | 233.41 ± 45.94 | 738.55 ± 36.4 | 173.98 ± 10.38 | 90.78 ± 9.45 |
2-Methylbutanal dimer | C96173 | C5H10O | 86.1 | 661.8 | 177.99 | 1.40 | 1432.09 ± 65.61 | 909.09 ± 49.14 | 674.59 ± 72.26 | 495.8 ± 36.75 |
2-Methylbutanal monomer | C96173 | C5H10O | 86.1 | 659.7 | 177.00 | 1.16 | 401.75 ± 14.95 | 301.28 ± 4.45 | 443.43 ± 6.92 | 492.91 ± 20.22 |
2-Pentenal (E) dimer | C1576870 | C5H8O | 84.1 | 745.3 | 238.45 | 1.37 | 54.63 ± 6.98 | 120.37 ± 5.89 | 243.18 ± 31.99 | 33.63 ± 2.47 |
2-Pentenal (E) monomer | C1576870 | C5H8O | 84.1 | 745.6 | 238.71 | 1.11 | 165.33 ± 11.36 | 200.09 ± 3.45 | 426.63 ± 36.76 | 152.51 ± 7.41 |
2-Pentylfuran | C3777693 | C9H14O | 138.2 | 1001.9 | 598.78 | 1.24 | 212.31 ± 21.79 | 1327.04 ± 82.25 | 263.66 ± 30.66 | 172.3 ± 2.81 |
3-Methylbutanal dimer | C590863 | C5H10O | 86.1 | 652.4 | 173.54 | 1.41 | 979.83 ± 46.43 | 458.85 ± 29.25 | 219.49 ± 28.19 | 218.41 ± 19.24 |
3-Methylbutanal monomer | C590863 | C5H10O | 86.1 | 649.7 | 172.30 | 1.17 | 310.93 ± 22.26 | 252.22 ± 6.09 | 251.21 ± 4.01 | 312.4 ± 14.22 |
3-Octanol dimer | C589980 | C8H18O | 130.2 | 983.5 | 565.02 | 1.77 | 27.63 ± 0.35 | 109.59 ± 5.66 | 32.29 ± 3.77 | 31.99 ± 6.66 |
3-Octanol monomer | C589980 | C8H18O | 130.2 | 984.2 | 566.23 | 1.39 | 218.74 ± 9.55 | 437.37 ± 27.6 | 232.78 ± 8.53 | 154.96 ± 5.27 |
5-Methyl-2-furanmethanol dimer | C3857258 | C6H8O2 | 112.1 | 954.5 | 511.57 | 1.57 | 197.92 ± 22.36 | 59.33 ± 1.58 | 149.97 ± 7.99 | 102.93 ± 8.99 |
5-Methyl-2-furanmethanol monomer | C3857258 | C6H8O2 | 112.1 | 955.8 | 513.98 | 1.26 | 511.85 ± 51.91 | 411.24 ± 14.62 | 664.63 ± 13.69 | 355.18 ± 8.68 |
6-Methyl-5-hepten-2-one | C110930 | C8H14O | 126.2 | 994.7 | 585.52 | 1.18 | 2100.88 ± 193.06 | 4922.49 ± 108.53 | 8939.93 ± 89.23 | 6135.18 ± 243.3 |
Acetone | C67641 | C3H6O | 58.1 | 541.7 | 121.11 | 1.12 | 307.59 ± 31.17 | 3941.64 ± 1000.18 | 279.57 ± 72.23 | 93.38 ± 8.36 |
benzaldehyde | C100527 | C7H6O | 106.1 | 955 | 512.56 | 1.15 | 422.9 ± 56.36 | 129.43 ± 5.64 | 251.34 ± 11.67 | 228.79 ± 1.29 |
Butyl acetate | C123864 | C6H12O2 | 116.2 | 804.6 | 294.95 | 1.24 | 21.92 ± 1.42 | 97.13 ± 4.61 | 38.21 ± 6.31 | 21.04 ± 2.4 |
Ethyl 2-methylbutanoate | C7452791 | C7H14O2 | 130.2 | 841.7 | 338.13 | 1.66 | 4068.59 ± 54.94 | 6201.27 ± 149.74 | 105.39 ± 2.41 | 45.64 ± 2.85 |
Ethyl 2-methylpropanoate | C97621 | C6H12O2 | 116.2 | 749.8 | 242.27 | 1.57 | 45.89 ± 10.29 | 544.37 ± 4.24 | 23.53 ± 1.3 | 23.09 ± 3.23 |
Ethyl butyrate | C105544 | C6H12O2 | 116.2 | 800.4 | 290.03 | 1.21 | 13.06 ± 0.52 | 79.82 ± 7.13 | 12.84 ± 1.66 | 12.24 ± 1.95 |
Heptanal dimer | C111717 | C7H14O | 114.2 | 899.4 | 410.27 | 1.70 | 684.87 ± 46.75 | 285.09 ± 14.02 | 780.97 ± 35.21 | 395.66 ± 12.06 |
Heptanal monomer | C111717 | C7H14O | 114.2 | 899.3 | 409.93 | 1.33 | 281 ± 21.65 | 212.67 ± 8.64 | 296.56 ± 11.67 | 71.12 ± 2.49 |
Heptanoic acid dimer | C111148 | C7H14O2 | 130.2 | 1053 | 693.30 | 1.76 | 91.78 ± 6.98 | 1362.95 ± 189.03 | 190.7 ± 22.46 | 81.34 ± 6.96 |
Heptanoic acid monomer | C111148 | C7H14O2 | 130.2 | 1051.6 | 690.58 | 1.36 | 217.9 ± 9.68 | 457.72 ± 51.97 | 86.71 ± 5.29 | 60.26 ± 1.53 |
Hexanal dimer | C66251 | C6H12O | 100.2 | 791.1 | 279.29 | 1.57 | 1899.55 ± 72.68 | 2897.65 ± 52.78 | 2694.57 ± 86.19 | 1494.49 ± 19.81 |
Hexanal monomer | C66251 | C6H12O | 100.2 | 791.1 | 279.29 | 1.26 | 1088.22 ± 49.57 | 1063.24 ± 43.75 | 1230.44 ± 37.1 | 1166.24 ± 21.4 |
Isoamyl acetate dimer | C123922 | C7H14O2 | 130.2 | 876 | 378.14 | 1.75 | 26.48 ± 6.98 | 144.48 ± 13.61 | 20.43 ± 1.35 | 20.8 ± 2.31 |
Isoamyl acetate monomer | C123922 | C7H14O2 | 130.2 | 876.6 | 378.85 | 1.30 | 66.4 ± 4.29 | 395.1 ± 12.85 | 102.52 ± 8.51 | 54.28 ± 6.8 |
Linalool oxide dimer | C60047178 | C10H18O2 | 170.3 | 1076.6 | 736.77 | 1.82 | 89.87 ± 6.51 | 450.59 ± 73.39 | 63.83 ± 5.24 | 49.68 ± 5.15 |
Linalool oxide monomer | C60047178 | C10H18O2 | 170.3 | 1077 | 737.67 | 1.26 | 326.91 ± 24.45 | 804.93 ± 72.82 | 74.35 ± 25.8 | 34.87 ± 2.02 |
Methyl 2-methylbutanoate dimer | C868575 | C6H12O2 | 116.2 | 768.8 | 258.26 | 1.54 | 217.3 ± 9.99 | 252.67 ± 7.51 | 24.62 ± 2.9 | 15.52 ± 1.03 |
Methyl 2-methylbutanoate monomer | C868575 | C6H12O2 | 116.2 | 770 | 259.28 | 1.18 | 404.26 ± 20.26 | 352.79 ± 23.05 | 211.43 ± 8.69 | 146.93 ± 5.49 |
Pentanal dimer | C110623 | C5H10O | 86.1 | 694.6 | 195.77 | 1.43 | 1044.79 ± 43.21 | 923.43 ± 31.09 | 1084.99 ± 23.53 | 1093.19 ± 19.8 |
Pentanal monomer | C110623 | C5H10O | 86.1 | 694.9 | 196.05 | 1.18 | 964.72 ± 56.23 | 1044.44 ± 46.97 | 749.54 ± 55.68 | 321.03 ± 3.04 |
Propylacetate dimer | C109604 | C5H10O2 | 102.1 | 707.7 | 206.83 | 1.48 | 39.05 ± 17.76 | 420.42 ± 8.88 | 27.48 ± 7.19 | 20.46 ± 0.21 |
Propylacetate monomer | C109604 | C5H10O2 | 102.1 | 708.4 | 207.36 | 1.17 | 64.59 ± 6.93 | 292.21 ± 5.69 | 71.38 ± 3.49 | 83.29 ± 4.01 |
Propylsulfide | C111477 | C6H14S | 118.2 | 884.7 | 388.21 | 1.16 | 42.7 ± 2.2 | 39.03 ± 1.77 | 226.35 ± 16.02 | 80.77 ± 4.8 |