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. 2021 Nov 26;13(23):4125. doi: 10.3390/polym13234125

Table 8.

Crystallization half times and Avrami constants for PLA samples at different temperatures.

Sample Temperature (°C) t1/2 (min) n ln k k
Neat PLA 90 20.03 2.520 −7.919 3.64 × 10−4
95 8.36 1.890 −4.380 1.25 × 10−2
100 6.83 2.320 −4.825 8.03 × 10−3
105 7.32 2.420 −5.184 5.61 × 10−3
110 12.21 2.240 −5.972 2.55 × 10−3
PLA + 1% MTPS 90 8.12 2.198 −4.969 6.95 × 10−3
95 4.19 2.127 −3.412 3.30 × 10−2
100 2.03 1.797 −1.641 1.94 × 10−1
110 2.91 2.084 −2.593 7.48 × 10−2
PLA + 2% MTPS 90 7.54 2.619 −5.657 3.49 × 10−3
95 3.83 1.964 −3.004 4.96 × 10−2
100 1.66 1.811 −1.289 2.76 × 10−1
105 2.10 1.946 −1.809 1.64 × 10−1
110 2.55 1.958 −2.200 1.11 × 10−1
PLA + 5% MTPS 90 2.94 1.960 −2.479 8.38 × 10−2
95 1.06 1.410 −0.447 6.40 × 10−1
100 0.94 2.010 −0.242 7.85 × 10−1
105 0.82 1.780 −0.018 9.82 × 10−1
110 1.12 1.740 −0.566 5.68 × 10−1