Fig. 2. Cyclic voltammograms of Ce^III/Ce^IV and Bk^III/Bk^IV terpyridine derivatives in THF and electrochemical data.

Potential scan rates of 10 (gray), 50 (yellow), and 100 (red) mV s⁻¹ were used. a Voltammograms showing the oxidation (III/IV) and reduction (IV/III) of the Bk/Terpy* complex, in 0.1 M BArF (supporting electrolyte). b Voltammograms showing the oxidation (III/IV) and reduction (IV/III) of the Ce/Terpy complex, in 0.1 M TBA PF₆ (supporting electrolyte). All data have been corrected to zero volts vs. an internal Fc/Fc⁺ reference.