Table 7.
Corrosion inhibiting admixtures in concrete.
Exposure Conditions |
Type of Inhibitor | Name of Inhibitor | Dosage of Inhibitor | Aggressive Conditions/Dosage | Efficiency (%) |
Reference |
---|---|---|---|---|---|---|
Ternary cement extract | Anodic/ Inorganic |
Calcium nitrite | 0% | 1% of Cl- | - | [198] |
2% of Cl- | - | |||||
3% of Cl- | - | |||||
0.5% | 1% of Cl- | 91 | ||||
2% of Cl- | 89 | |||||
3% of Cl- | 81 | |||||
Portland pozzolona Cement extract | Sodium hydroxide | 0 wt % of cement | 30,000 ppm Cl− | - | [193] | |
1 wt % of cement | 7.47 | |||||
Sodium hydroxide + sodium citrate | 1 wt % of cement | 30,000 ppm Cl− | 12.52 | |||
Sodium hydroxide + sodium citrate + sodium stannate | 33.43 | |||||
Sodium hydroxide + sodium citrate + sodium stannate + CaO | 45.15 | |||||
Sat. Ca(OH)2 | Lithium nitrite | 8.94(g/L) | 0.99 NaCl(g/L) | 85.75 | [199] | |
17.21(g/L) | 83.26 | |||||
Concrete medium | NaNO2 | 0% | 3% NaCl | - | [157] | |
1% | 87.9 | |||||
2% | 87.1 | |||||
3% | 85.83 | |||||
ZnO | 1% | 93.75 | ||||
2% | 94.16 | |||||
3% | 91.66 | |||||
NaNO2 + ZnO | 1% | 95.83 | ||||
2% | 94.58 | |||||
3% | 93.75 | |||||
SCPS | NaNO2 | 1500 ppm | 3.5% NaCl | 55% | [200] | |
Trisodium Citrate | 150 ppm | 72.5 | ||||
Zinc Acetate | 50 ppm | 55 | ||||
Zinc Acetate + Trisodium citrate | 50 ppm + 100 ppm | 78 | ||||
Cement mortar | Anodic/ Inorganic |
Sodium nitrate | 0.4 mol per 1 kg cement | 3.5% NaCl (360 days) | 21.4 | [201] |
Cathodic/ Inorganic |
Sodium phosphate | 7.5 | ||||
Sodium phosphate | 7% (by wt. of cement) | 1% of Cl- (by wt. of cement) (360 days) | 97.7 | [202] | ||
Carbonated concrete solutions (0.0315 mol/L) | DiSodium Hydrogen Phosphate | 20 mmol/L | 0.1 mol/L NaCl | 52 | [203] | |
60 mmol/L | 93 | |||||
100 mmol/L | 99.95 | |||||
Chloride contaminated cement mortar(3% of NaCl (wt%)) | Sodiumpyro phosphate | 0% | - | - | [204] | |
0.3% | - | 78 | ||||
0.6% | - | 89 | ||||
1.2% | - | 58 | ||||
2.4% | - | 46 | ||||
Cement Concrete | Organic | Monoethanolamine | 1% | exposed to 3% NaCl | 49.58 | [157] |
2% | 50.8 | |||||
3% | 38.75 | |||||
Diethonolamine | 1% | exposed to 3% NaCl | 35.42 | |||
2% | 28.33 | |||||
3% | 39.16 | |||||
Triethonalamine | 1% | exposed to 3% NaCl | 77.04 | |||
2% | 62.5 | |||||
3% | 53.33 | |||||
Sat.Ca(OH)2 | Organic | Deoxyribonucleic acid | 0.0050 % | 0.01 mol/L NaCl add every day (7 Days) | 58.60 | [205] |
Dicyclohexyl ammonium nitrite | Sat. | 0.1 M NaCl | 97 | |||
5-Hexyl-benzotriazole | 0.005 M | 0.1 M NaCl | 67 | |||
Sodium β-glycerophosphate | 0.05 M | 0.1 M NaCl | 92 | |||
Cement Mortar | Organic | Dicyclohexyl ammonium nitrite | 0.5(In/Cl- ratio) | 0.02 Cl−/cement wt. ratio | 88 | [205] |
Sodium β-glycerophosphate | 90 | |||||
Carbonated alkali-activated fly ash mortar | Organic | Disodium β-glycerol phosphate Pentahydrate + sodium 3-aminobenzoate | 0.05 M + 0.05 M | Immersed in 1% NaCl | 63 | [206] |
Disodium β-glycerol phosphate pentahydrate + sodium N-phenylanthranilate | 0.05 M + saturated | 81 |