Table 6.
T / K | 1014 κ0φ / m3 mol-1 Pa-1 | 1014 Bk / kg m3 mol-2 Pa-1 | 1014 ∆trκ0φ / m3 mol-1 Pa-1 | σ (κφ) |
---|---|---|---|---|
PTH in ethanol | ||||
288.15 | − 1.05 | − 73.63 | – | 0.12 |
298.15 | − 2.71 | − 65.09 | – | 0.13 |
308.15 | − 3.76 | − 71.08 | – | 0.16 |
318.15 | − 4.83 | − 71.05 | – | 0.07 |
PTH in ternary ethanol solution of ChCl:Gly (0.5 mol kg-1) | ||||
288.15 | − 1.90 | − 75.83 | − 0.85 | 0.11 |
298.15 | − 2.86 | − 75.57 | − 0.15 | 0.13 |
308.15 | − 3.94 | − 73.47 | − 0.18 | 0.21 |
318.15 | − 4.49 | − 77.56 | 0.34 | 0.10 |
PTH in ternary ethanol solution of ChCl:Gly (1 mol kg-1) | ||||
288.15 | − 3.54 | − 42.28 | − 2.49 | 0.06 |
298.15 | − 4.84 | − 50.47 | − 2.13 | 0.09 |
308.15 | − 6.26 | − 49.74 | − 2.50 | 0.07 |
318.15 | − 7.73 | − 54.31 | − 2.90 | 0.09 |
PTH in ternary ethanol solution of ChCl:Gly (1.5 mol kg-1) | ||||
288.15 | − 4.40 | − 32.00 | − 3.35 | 0.06 |
298.15 | − 5.92 | − 41.48 | − 3.21 | 0.05 |
308.15 | − 7.60 | − 38.55 | − 3.84 | 0.05 |
318.15 | − 9.45 | − 35.34 | − 4.62 | 0.08 |
PTH in ternary ethanol solution of ChCl:EG (0.5 mol kg-1) | ||||
288.15 | − 3.42 | − 69.69 | − 2.37 | 0.08 |
298.15 | − 3.87 | − 68.05 | − 1.16 | 0.07 |
308.15 | − 4.83 | − 60.95 | − 1.07 | 0.06 |
318.15 | − 5.22 | − 65.56 | − 0.39 | 0.08 |
PTH in ternary ethanol solution of ChCl:EG (1 mol kg-1) | ||||
288.15 | − 5.22 | − 26.42 | − 4.17 | 0.04 |
298.15 | − 6.66 | − 26.60 | − 3.95 | 0.06 |
308.15 | − 8.42 | − 25.73 | − 4.66 | 0.07 |
318.15 | − 10.15 | − 29.64 | − 5.32 | 0.08 |
PTH in ternary ethanol solution of ChCl:EG (1.5 mol kg-1) | ||||
288.15 | − 6.11 | − 35.13 | − 5.06 | 0.10 |
298.15 | − 7.61 | − 35.35 | − 4.90 | 0.08 |
308.15 | − 9.37 | − 36.41 | − 5.61 | 0.10 |
318.15 | − 11.33 | − 40.50 | − 6.50 | 0.10 |
Standard uncertainty (u) for DESs composition was estimated to be less than 5·10–2 mol ratio.