TABLE 2.

The retention time and MS data of 78 compounds in fruit detected by UPLC–MS/MS.

No	Compounds	RT (min)	Molecular formula	Molecular weight	[M + H]	[M–H]	[M + Na]
1	Sophoramine	0.726	C15H21N2O	245.1654	√	—	—
2	Alopecurone A	0.780	C39H37O9	649.2438	—	√	—
3	Kushenol W	0.815	C21H21O7	385.1287	—	√	—
4	Cinnamic acid	0.841	C9H7O2	147.0446	—	√	—
5	Alopecurone B	0.866	C39H37O9	649.2438	—	√	—
6	Quercetin	0.892	C15H11O7	303.0505	√	—	—
7	Sophocarpine	0.936	C15H23N2O	247.1810	√	—	—
8	Kaushenol N	0.954	C26H31O7	455.2070	√	—	—
9	Daidzein	0.963	C15H13O4	257.0814	—	√	—
10	Sparteine	0.989	C15H27N2	235.2174	√	—	—
11	Aloperine	1.049	C15H25N2	233.2018	√	—	—
12	Secundiflorol A	1.155	C21H23O8	403.1393	√	—	—
13	Kushenol L	1.312	C25H29O7	441.1913	—	√	—
14	Leachianone G	1.460	C20H21O6	357.1338	√	—	—
15	Sophoraisoflavanone A	1.521	C20H18O6	353.1025	√	—	—
16	Kushenol B	1.547	C30H37O6	493.2590	√	—	—
17	Caffeic acid	1.573	C9H9O4	181.0501	√	—	—
18	Gallic acid	1.609	C7H5O5	169.0137	—	√	—
19	Luteoloside	1.686	C21H21O11	449.1084	—	√	—
20	Kaushenol H	2.018	C26H31O7	455.2070	√	—	—
21	Benzoic acid	2.237	C7H5O2	121.0290	—	√	—
22	Ferulic acid	2.534	C10H9O4	193.0501	—	√	—
23	N-Methylaytisine	3.773	C12H16N2O	205.1341	√	—	—
24	LupinifoLin	3.957	C25H25O5	405.1702	—	√	—
25	Secundiflorol D	4.035	C21H23O6	371.1495	√	—	—
26	Kushenol Q	4.183	C25H29O7	441.1913	—	√	—
27	Rutin	4.315	C27H29O16	609.1456	—	√	—
28	Daidzin	4.324	C21H21O9	417.1186	√	—	—
29	Matrine	4.375	C15H25N2O	249.1967	√	—	—
30	Sophoraisoflavanone D	4.402	C30H37O6	493.2590	√	—	—
31	Vicenin–2	4.428	C27H29O15	593.1509	—	√	—
32	Sophoricoside	4.515	C21H19O10	431.0978	—	√	—
33	Isokurarinone	4.550	C26H29O6	437.1964	—	√	—
34	Kurarinol	4.576	C26H31O7	455.2070	—	√	—
35	Saponarin	4.585	C27H29O15	593.1509	—	√	—
36	Isosakuranin	4.594	C22H23O10	447.1291	—	√	—
37	Sophoridine	4.595	C15H25N2O	249.1967	√	—	—
38	Kushenol X	4.638	C25H29O7	441.1913	—	√	—
39	Echinoisoflavanone	4.655	C22H25O7	401.1600	√	—	—
40	(2S) –2′–methoxykurarinone	4.733	C27H33O6	453.2277	√	—	—
41	Chlorogenic acid	4.917	C16H17O9	353.0873	—	√	—
42	Kushenol C	4.934	C25H25O7	437.1600	—	√	—
43	Triterpene	4.943	C22H21O10	445.1135	—	√	—
44	Kurarinone	4.943	C26H29O6	437.1964	—	√	—
45	Alopecurone D	4.952	C40H39O9	663.2594	—	√	—
46	Epicatechin	4.978	C15H13O6	289.0712	—	√	—
47	Erythrabrssin II	4.987	C25H29O4	393.2066	√	—	—
50	Kuraridinol	5.178	C26H31O7	455.2070	—	√	—
51	Diosmetin	5.589	C16H13O6	301.0712	√	—	—
52	Cytisine	5.702	C11H14N2ONa	213.1004	—	—	√
53	Isoquerctrin	5.807	C21H19O12	463.0877	—	√	—
54	Exiguaflavanone D	6.042	C30H37O7	509.2539	—	√	—
55	Sophpraflavanone B	6.504	C20H19O5	339.1232	—	√	—
56	Kushenol K	6.889	C27H31O6	483.2019	—	√	—
57	Kushenol U	7.099	C25H29O5	409.2015	—	√	—
58	Luteolin	7.508	C15H9O6	285.0399	—	√	—
59	Alopecurone J	8.198	C39H37O9	649.2438	—	√	—
60	Alopecurone K	8.609	C39H37O9	649.2438	—	√	—
61	Sophoraflavanone I	8.949	C39H37O9	649.2438	—	√	—
62	Sophoranone	8.992	C30H35O5	475.2484	—	√	—
63	Maackiain	9.323	C16H11O5	283.0606	—	√	—
64	Kushenol T	9.324	C25H31O6	427.2121	√	—	—
65	Norkurarinone	9.630	C25H29O6	425.1964	√	—	—
66	Leachianone B	9.672	C26H29O6	437.1964	—	√	—
67	Leachianone A	9.962	C26H29O6	437.1964	—	√	—
68	Sophoraflavanone H	10.179	C34H31O9	583.1968	√	—	—
69	Alopecurone G	10.240	C26H29O5	421.1025	—	√	—
70	Flavenochromane C	10.764	C24H25O6	421.1615	—	√	—
71	Secundiflorol E	10.765	C22H25O7	401.1600	√	—	—
72	Isosophoranone	10.807	C26H29O6	437.1964	—	√	—
73	8–Lavandulylkaempferol	10.948	C24H25O6	421.1615	—	√	—
74	Orientin	11.514	C21H19O11	447.0927	—	√	—
75	Sophpraflavanone G	12.073	C25H27O6	423.1808	—	√	—
76	Desmethylanhydroicaritin	12.222	C20H17O6	353.1025	—	√	—
77	Daucosterol	13.984	C35H59O6	575.4312	—	√	—
78	Kushenol S	14.289	C20H19O5	339.1232	—	√	—