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. 2021 Dec 22;8(12):211527. doi: 10.1098/rsos.211527

Table 2.

Various physico-chemical parameters for IMP + BZCl mixed systems in various media at 298.15 K.a

α1 cmc (mmol kg−1) cmcid (mmol kg−1) X1m X1id βm f1m f2m ln (cmc1/cmc2)
aqueous solution
 0 41.85
 0.1 10.20 18.05 0.552 0.612 −2.34 0.626 0.490
 0.3 6.07 8.44 0.720 0.859 −1.97 0.857 0.361
 0.5 3.97 5.51 0.772 0.934 −2.65 0.872 0.206 −2.65
 0.7 3.60 4.09 0.879 0.971 −2.0 0.971 0.214
 0.9 2.72 3.25 0.878 0.992 −3.80 0.945 0.053
 1 2.95
50 mmol kg−1 NaCl
 0 37.25
 0.1 4.56 15.66 0.535 0.622 −5.03 0.338 0.237
 0.3 2.38 7.26 0.622 0.864 −5.52 0.455 0.118
 0.5 1.15 4.72 0.637 0.937 −7.79 0.358 0.043 −2.69
 0.7 0.79 3.50 0.656 0.972 −9.27 0.334 0.019
 0.9 0.58 2.78 0.679 0.993 −11.5 0.305 0.005
 1 2.52
300 mmol kg−1 urea
 0 45.20
 0.1 12.05 20.13 0.549 0.599 −2.10 0.653 0.532
 0.3 7.20 9.54 0.728 0.852 −1.69 0.883 0.408
 0.5 5.15 6.26 0.815 0.931 −1.79 0.940 0.304 −2.60
 0.7 4.0 4.65 0.866 0.969 −2.16 0.962 0.198
 0.9 2.90 3.70 0.853 0.992 −4.31 0.911 0.044
 1 3.36
300 mmol kg−1 thiourea
 0 46.0
 0.1 12.5 20.70 0.547 0.595 −2.06 0.656 0.540
 0.3 7.52 9.86 0.730 0.850 −1.63 0.888 0.421
 0.5 5.35 6.47 0.816 0.929 −1.74 0.943 0.315 −2.58
 0.7 4.15 4.82 0.867 0.969 −2.13 0.963 0.202
 0.9 3.01 3.83 0.853 0.992 −4.28 0.912 0.044
 1 3.48

aStandard uncertainties (u) are u(T) = 0.20 K, u(NaCl) = 1 mmol kg−1, u(urea) = 2 mmol kg−1, u(thiourea) = 2 mmol kg−1 and u(p) = 5 kPa (level of confidence = 0.68). Relative standard uncertainties (ur) are ur(cmc/cmcid) = ±3%, ur(X1m/X1id)=±3%, ur(βm) = ±3% and ur(f1m/f2m)=±4%.