Table 2.
α1 | cmc (mmol kg−1) | cmcid (mmol kg−1) | ln (cmc1/cmc2) | |||||
---|---|---|---|---|---|---|---|---|
aqueous solution | ||||||||
0 | 41.85 | |||||||
0.1 | 10.20 | 18.05 | 0.552 | 0.612 | −2.34 | 0.626 | 0.490 | |
0.3 | 6.07 | 8.44 | 0.720 | 0.859 | −1.97 | 0.857 | 0.361 | |
0.5 | 3.97 | 5.51 | 0.772 | 0.934 | −2.65 | 0.872 | 0.206 | −2.65 |
0.7 | 3.60 | 4.09 | 0.879 | 0.971 | −2.0 | 0.971 | 0.214 | |
0.9 | 2.72 | 3.25 | 0.878 | 0.992 | −3.80 | 0.945 | 0.053 | |
1 | 2.95 | |||||||
50 mmol kg−1 NaCl | ||||||||
0 | 37.25 | |||||||
0.1 | 4.56 | 15.66 | 0.535 | 0.622 | −5.03 | 0.338 | 0.237 | |
0.3 | 2.38 | 7.26 | 0.622 | 0.864 | −5.52 | 0.455 | 0.118 | |
0.5 | 1.15 | 4.72 | 0.637 | 0.937 | −7.79 | 0.358 | 0.043 | −2.69 |
0.7 | 0.79 | 3.50 | 0.656 | 0.972 | −9.27 | 0.334 | 0.019 | |
0.9 | 0.58 | 2.78 | 0.679 | 0.993 | −11.5 | 0.305 | 0.005 | |
1 | 2.52 | |||||||
300 mmol kg−1 urea | ||||||||
0 | 45.20 | |||||||
0.1 | 12.05 | 20.13 | 0.549 | 0.599 | −2.10 | 0.653 | 0.532 | |
0.3 | 7.20 | 9.54 | 0.728 | 0.852 | −1.69 | 0.883 | 0.408 | |
0.5 | 5.15 | 6.26 | 0.815 | 0.931 | −1.79 | 0.940 | 0.304 | −2.60 |
0.7 | 4.0 | 4.65 | 0.866 | 0.969 | −2.16 | 0.962 | 0.198 | |
0.9 | 2.90 | 3.70 | 0.853 | 0.992 | −4.31 | 0.911 | 0.044 | |
1 | 3.36 | |||||||
300 mmol kg−1 thiourea | ||||||||
0 | 46.0 | |||||||
0.1 | 12.5 | 20.70 | 0.547 | 0.595 | −2.06 | 0.656 | 0.540 | |
0.3 | 7.52 | 9.86 | 0.730 | 0.850 | −1.63 | 0.888 | 0.421 | |
0.5 | 5.35 | 6.47 | 0.816 | 0.929 | −1.74 | 0.943 | 0.315 | −2.58 |
0.7 | 4.15 | 4.82 | 0.867 | 0.969 | −2.13 | 0.963 | 0.202 | |
0.9 | 3.01 | 3.83 | 0.853 | 0.992 | −4.28 | 0.912 | 0.044 | |
1 | 3.48 |
aStandard uncertainties (u) are u(T) = 0.20 K, u(NaCl) = 1 mmol kg−1, u(urea) = 2 mmol kg−1, u(thiourea) = 2 mmol kg−1 and u(p) = 5 kPa (level of confidence = 0.68). Relative standard uncertainties (ur) are ur(cmc/cmcid) = ±3%, ur(βm) = ±3% and .