. 2021 Dec 22;8(12):211527. doi: 10.1098/rsos.211527

Table 4.

Numerous thermodynamic parameters and packing parameter (P) for IMP + BZCl mixed systems in various solvents at 298.15 K.^a

α₁	$Δ G_{mic}^{\circ} (kJ {mol}^{- 1})$	$Δ G_{ad}^{\circ}$ (kJ mol⁻¹)	G_min (kJ mol⁻¹)	$Δ G_{ex}^{m} (kJ {mol}^{- 1})$	$Δ G_{ex}^{σ} (kJ {mol}^{- 1})$	p-value
aqueous system
0	−17.8	−40.1	33.3			0.34
0.1	−21.3	−40.5	17.8	−1.43	−2.23	0.50
0.3	−22.6	−44.8	21.7	−0.98	−2.44	0.42
0.5	−23.7	−46.4	22.9	−1.15	−2.85	0.41
0.7	−23.9	−45.4	22.6	−0.52	−1.99	0.42
0.9	−24.6	−49.8	25.4	−1.01	−3.81	0.37
1	−24.4	−44.7	21.9			0.45
50 mmol kg⁻¹ NaCl
0	−18.1	−47.8	50.4			0.24
0.1	−23.3	−58.6	30.4	−3.10	−4.06	0.28
0.3	−24.9	−56.3	27.2	−3.21	−1.74	0.32
0.5	−26.7	−55.9	25.1	−4.46	−1.86	0.34
0.7	−27.7	−56.3	24.6	−5.18	−2.57	0.35
0.9	−28.4	−57.8	25.3	−6.23	−3.54	0.34
1	−24.8	−66.6	35.7			0.24
300 mmol kg⁻¹ urea
0	−17.6	−33.2	27.4			0.44
0.1	−20.9	−41.1	18.8	−1.29	−1.59	0.48
0.3	−22.2	−48.7	25.2	−0.83	−2.18	0.36
0.5	−23.0	−48.6	26.1	−0.67	−1.23	0.36
0.7	−23.6	−56.9	33.8	−0.62	−3.89	0.28
0.9	−24.4	−49.8	26.2	−1.34	−1.59	0.36
1	−24.1	−50.7	28.7			0.34
300 mmol kg⁻¹ thiourea
0	−17.58	−32.9	30.8			0.41
0.1	−20.81	−48.8	24.2	−1.26	−2.65	0.36
0.3	−22.07	−52.3	26.0	−0.79	−2.13	0.33
0.5	−22.91	−54.5	28.3	−0.65	−1.83	0.31
0.7	−23.54	−54.8	27.7	−0.61	−2.09	0.32
0.9	−24.34	−57.1	29.2	−1.33	−3.31	0.30
1	−23.98	−63.4	33.5			0.26

^aStandard uncertainties (u) are u(T) = 0.20 K, u(NaCl) = 1 mmol kg⁻¹, u(urea) = 2 mmol kg⁻¹, u(thiourea) = 2 mmol kg⁻¹ and u(p) = 5 kPa (level of confidence = 0.68). Relative standard uncertainties (u_r) are $u_{r} (Δ G_{m}^{o}) = \pm 3 %$ , $u_{r} (Δ G_{ads}^{o}) = \pm 4 %$ , u_r(G_min) = ±4%, $u_{r} (Δ G_{ex}^{m} / Δ G_{ex}^{σ}) = \pm 5 % and u_{r} (p) = \pm 4 %$ .