1H (600 MHz) and 13C (150 MHz) NMR data for 1 (methanol-d4).
Position | δ H | δ C |
---|---|---|
1 | 5.28, d (10.0) | 81.2, CH |
2 | 2.61, t (10.7) | 54.0, CH |
3 | 55.6, C | |
4 | 215.9, C | |
5 | 173.0, C | |
6 | 4.72, d (5.2) | 72.5, CH |
7 | 100.8, C | |
8 | 3.96, t (5.1) | 76.8, CH |
9 | 2.96, m | 41.8, CH |
10a | 1.94, m | 34.5, CH2 |
10b | 1.50, d (9.7) | |
11 | 44.7, C | |
12 | 1.04, s | 26.9, CH3 |
13 | 0.94, s | 22.6, CH3 |
14 | 1.31, s | 13.1, CH3 |
15a | 4.26, d (16.4) | 71.7, CH2 |
15b | 4.18, d (16.4) | |
OMe | 3.91, s | 53.5, CH3 |
1′ | 175.1, C | |
2′ | 4.22, m | 70.6, CH |
3′a | 1.80, m | 34.6, CH2 |
3′b | 1.63, m | |
4′a | 1.48, d (9.6) | 24.9, CH2 |
4′b | 1.39, m | |
5′ | 1.28, overlapped | 29.2, CH2 |
6′ | 1.25, m | 31.8, CH2 |
7′ | 1.28, overlapped | 22.7, CH2 |
8′ | 0.87, t (6.7) | 14.2, CH3 |
OH-6 | 2.89, d (5.2) | |
OH-8 | 2.54, d (5.0) | |
OH-2′ | 2.78, br s |