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. 2020 Dec 24;11(2):637–656. doi: 10.1039/d0ra07141b

Melt processing strategies and parameters of cellulose-reinforced polyamides.

Author – year article Matrix Cellulose type Processing aid/compatibilizer/surface functionalization Processing techniques Cellulose (wt%)
(Klason, Kubát, & Strömvall, 1984)12 PA6, PA12 Wood flour, bleached cellulose flour, bleached CF, all oven dried@105 °C/24 h Neat Internal mixer, extrusion (single-screw), injection moulding [PA12 max 195 °C; PA6 max 235 °C] 10.0–30.0
(Jacobson, Caulfield, Sears, Underwood, & Caufield, 2001)70 PA6, PA66 CF – oven dried at 105 °C Processing aid: 0003–0005 wt% of carboxy methylcellulose (CMC) viscosity modifier Extrusion (twin-screw), injection moulding [max 232 °C] 33.0
(Lu, Doyle, & Li, 2007)58 PA12 Wood flour, oven dried@103 °C/24 h Neat Internal mixer, compression moulding [max 200 °C] 40.0–60.0
(Xiaolin, 2008)65 PA6, PA66 CF – oven dried@120 °C/4 h Neat binder: polyurethane aq. dispersion-Hydrosize U1-01, plasticizers: (NBBSA), caprolactam, thiurea, ceramic powder (INTEC SB 94), lithium chloride (LiCl) Extrusion (twin-screw), injection moulding, compression moulding [max 270°] 10.0–30.0
(Chen, Gardner, 2008)135 PA6 & PA66 blend Wood flour Processing aid, 7 wt% (unknown) Extrusion (single screw), (Davis standard Woodtruder) [max N/A] 43.0
(Arcaya et al., 2009)136 PA6, PA66 Natural fibers (flax), pulp, CF, all vacuum oven dried (80 °C) Neat Internal mixer, injection moulding [max 265 °C] 20.0–35.0
(Panaitescu, Frone, & Nicolae, 2013)57 PA11 CNF – vacuum oven dried (60 °C) [H2SO4] Neat Internal mixer, two-roll mill, compression moulding [max 190 °C] 1.0–8.0
(Kiziltas, Gardner, Han, & Yang, 2014)59 PA6 MCC – oven dried@105 °C/16 h Lubricant – fatty acid esters (5 wt%) Internal mixer, injection moulding [max 250 °C] 2.5–30.0
(Bledzki, Feldmann, 2014)137 PA1010, PA 610 Man-made CF Neat Pultrusion, extrusion, (single screw), injection moulding [max 245 °C] 15.0–30.0
(Panaitescu, Gabor, Frone, & Vasile, 2015)18 PA11 CNF– vacuum oven dried (60 °C) [H2SO4] Neat Internal mixer, two-roll mill, compression moulding [max 190 °C], Annealing@165 °C/1 h 1.0–8.0
(Zhu, Kiziltas, Lee, & Mielewski, 2015)16 PA1010, PA 610 CNF – oven dried@70 °C Neat [masterbatch, N/A wt%] Extrusion (single screw), injection moulding [max 235 °C] 2.0–20.0
(Peng, Gardner, & Han, 2015)56 PA6 MCC – spray dried, CNF – spray dried, CNC – spray dried + oven dried@105 °C/12 h PA processing aid-viscosity lowering agent (3 wt%) Internal mixer, micro-injection moulding [max 270 °C] 2.5–10.0
(Nicharat, Sapkota, Weder, & Johan Foster, 2015)41 PA12 CNC – freeze dried [H3PO4 & H2SO4] Neat Internal mixer, compression moulding [max 190 °C] 5.0–20.0
(Armioun et al., 2016)78 PA11 Wood fiber – oven dried@105 °C/2 h Maleic anhydride grafted polypropylene (4 wt%) Extrusion (twin-screw), injection moulding [max 210 °C] 10.0–30.0
(Yousefian & Rodrigue, 2016)64 PA6 CNC – oven dried@70 °C/24 h Neat [masterbatch 10 wt%] Extrusion (twin-screw), injection moulding [max 230 °C] 1.0–7.0
(Zierdt et al., 2017)138 PA11 Wood fiber Neat Internal mixer, extrusion (twin-screw),Injection moulding [max 220 °C] 50.0
(Fernandes et al., 2017)139 PA6 CF – bleached and non-bleached Lubricant ethylene bis-stearamide (1 wt%) Extrusion (twin-screw), injection moulding [max 250 °C] 20.0–40.0
(Yousefian et al., 2017)140 PA6 CNC – oven dried@70 °C/24 h Neat foaming agent: azodicarbonamide (1–2 wt%) [masterbatch 5 wt%] Extrusion (twin-screw), injection moulding [max 230 °C] 0.5–5.0
(Rohner et al., 2018)67 PA11 Wood CNF – freeze dried, spinex grass CNF – freeze dried Neat Extrusion (twin-screw), injection moulding, compression moulding [max 215 °C] 0.1–0.5
(Xu et al., 2018)141 PA6 Wood fiber, oven dried@103 °C/24 h Lithium chloride (LiCl) (0–3%), chain extender: 2,2′-(1,4-phenylene)bis(2-oxazoline) (PBO) (0.2–1%) Internal mixer, compression moulding [max 235 °C] 20.0–40.0
(Beg et al., 2018)142 PA6.10 MCC, oven dried Impact modifier (IM), Exxelor VA1803 (2.0–5.0%) Extrusion (twin-screw), injection moulding [max 240 °C] 20.0–40.0
(Oliver-Ortega et al., 2018)143 PA11 Wood fiber Neat Kinetic mixer (twin-screw), injection moulding [max N/A] 20.0–60.0
(Gohn et al., 2019)81 PA12 CNC Neat Internal mixer, compression moulding [max 200 °C] 5.0
(Venkatraman et al., 2019)144 PA11 CNC Neat Planetary ball milling, internal mixer, compression moulding [max 200 °C] 10.0
(Annandarajah et al., 2019)145 PA6 CF Polypropylene maleic anhydride grafted polypropylene (PPgMA) [70 : 30 wt% ratio of PA6 : PP and 6 wt% PPgMA] Extrusion (twin-screw), injection moulding [max 220 °C] 30.0
(Beg et al., 2019)146 PA6.10 MCC, oven dried Coupling agent: Exxelor VA1803 (5.0%), coupling agent: Bondyram 7103 (BR) Extrusion (twin-screw), injection moulding, [max 240 °C] 30.0