Magnetic nanoparticles/functionalized magnetic nanoparticles-catalyzed synthesis of 1,4-DHPa.
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| Entry | Catalyst | Temperature (°C)/Ultrasonic Probe(W) | Solvent | Time (min) | Yieldb (%) | Ref. |
| 1 | γ-Fe2O3, MW, and fixed bed flow reactor | 100 | Solvent free | 5 | 93.5 | 69 |
| 2 | γ-Fe2O3@HAp@Melamine | 80 | Solvent free | 15 | 94 | 70 |
| 3 | Fe3O4/SiO2-PDA NPs/USW | Room temperature | EtOH | 10 | 89 | 71 |
| 4 | AIL-SCMNPs | 60 | Solvent free | 10 | 92 | 72 |
| 5 | Ultrasound Fe3O4@SiO2–SnCl4 | 40 | EtOH | 5 | 98 | 73 |
| 6 | Fe3O4@SiO2@ADMPT/HPA nano catalyst | 70 | EtOH | 35 | 92 | 74 |
| 7 | NiFe2O4@SiO2–H14NaP5W30O110 | 120 | Solvent free | 10 | 94 | 75 |
| 8 | Nano ZnFe2O4 | Room temperature | H2O | 30 | 90–96 | 76 |
| 9 | (a) Hal-Fe3O4 with 1,3-ketoesters | Reflux | EtOH | 20 | 96 | 77 |
| (b) Hal-Fe3O4 with dimedone | Reflux | EtOH | 20 | 94 | ||
| 10 | Fe3O4@IG | Ultrasound | EtOH | 50 | 88 | 78 |
| 11 | (a) γ-Fe2O3@Cu@cellulose for 1,4-dihydropyridine derivatives | Room temperature | Solvent free | Completion of reaction | 80–92 | 79 |
| (b) γ-Fe2O3@Cu@cellulose for polyhydroquinoline derivatives | Room temperature | Solvent free | 20 | 87–95 | ||
| 12 | Nano-FGT | 100–120 | Solvent free | 35 | 80–91 | 87 |
| 13 | Fe–C–O–Mo alloy | Reflux | EtOH | 150 | 92 | 88 |
| 14 | Chitosan NPs | 80 | Solvent free | 20 | 90 | 89 |
| 15 | Fe3O4@chitosan | Room temperature | EtOH | 30–140 | 84–98 | 90 |
| 16 | MGCS | Reflux | EtOH | 15 | 84–89 | 91 |
Reaction conditions: aldehyde (1.0 mmol), ethyl acetoacetate (2.0 mmol), NH4OAc (1–1.5 mmol), dimedone (2.0 mmol).
Isolated yields.