13C NMR data of compounds 1–14a.
| No. | 1b | 2b | 3b | 4b | 5b | 6b | 7c | 8b | 9b | 10b | 11b | 12b | 13b | 14b |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | 39.8 t | 39.8 t | 39.7 t | 39.8 t | 39.8 t | 39.7 t | 38.9 t | 39.8 t | 39.8 t | 39.8 t | 39.7 t | 39.7 t | 39.7 t | 39.7 t |
| 2 | 30.2 t | 30.2 t | 30.1 t | 30.2 t | 30.2 t | 30.1 t | 29.0 t | 30.2 t | 30.2 t | 30.2 t | 30.1 t | 30.1 t | 30.1 t | 30.1 t |
| 3 | 79.3 d | 79.3 d | 79.22 d | 79.4 d | 79.3 d | 79.3 d | 78.0 d | 79.3 d | 79.3 d | 79.3 d | 79.3 d | 79.3 d | 79.2 d | 79.2 d |
| 4 | 39.9 t | 39.8 t | 39.8 t | 39.9 t | 39.8 t | 39.8 t | 38.8 t | 39.8 t | 39.8 t | 39.8 t | 39.8 t | 39.8 t | 39.7 t | 39.8 t |
| 5 | 140.3 s | 140.1 s | 140.1 s | 140.3 s | 140.1 s | 140.1 s | 139.7 s | 140.0 s | 140.1 s | 140.1 s | 140.0 s | 140.1 s | 140.0 s | 140.1 s |
| 6 | 120.1 d | 120.0 d | 120.1 d | 120.0 d | 120.0 d | 119.8 d | 118.4 d | 120.0 d | 120.0 d | 120.0 d | 119.8 d | 119.8 d | 120.0 d | 119.8 d |
| 7 | 35.3 t | 35.3 t | 35.2 t | 35.3 t | 35.2 t | 35.2 t | 33.7 t | 35.2 t | 35.2 t | 35.2 t | 35.1 t | 35.1 t | 35.1 t | 35.1 t |
| 8 | 75.1 s | 75.0 s | 75.0 s | 75.1 s | 75.5 s | 75.0 s | 72.4 s | 75.0 s | 75.2 s | 75.2 s | 75.3 s | 75.4 s | 74.9 s | 75.5 s |
| 9 | 45.3 d | 44.8 d | 44.7 d | 45.4 d | 44.8 d | 44.6 d | 43.4 d | 44.7 d | 44.7 d | 44.7 d | 44.7 d | 44.7 d | 44.6 d | 44.7 d |
| 10 | 38.0 s | 38.1 s | 38.0 s | 38.0 s | 38.0 s | 38.0 s | 37.0 s | 38.0 s | 38.0 s | 38.0 s | 38.0 s | 38.0 s | 37.9 s | 38.0 s |
| 11 | 29.8 t | 26.0 t | 26.1 t | 29.8 t | 26.0 t | 26.3 t | 24.7 t | 26.0 t | 26.0 t | 26.0 t | 26.0 t | 26.0 t | 26.0 t | 26.0 t |
| 12 | 71.3 d | 75.5 d | 75.2 d | 71.3 d | 75.0 d | 75.5 d | 74.0 d | 75.1 d | 75.0 d | 75.0 d | 75.0 d | 75.0 d | 75.4 d | 75.0 d |
| 13 | 59.2 s | 57.7 s | 57.7 s | 58.1 s | 57.5 s | 57.8 s | 56.3 s | 57.6 s | 57.7 s | 57.4 s | 57.4 s | 54.8 s | 57.3 s | 57.4 s |
| 14 | 89.5 s | 89.2 s | 88.5 s | 88.9 s | 89.1 s | 88.6 s | 87.9 s | 89.2 s | 89.2 s | 89.2 s | 88.5 s | 88.5 s | 88.4 s | 88.5 s |
| 15 | 34.2 t | 34.4 t | 34.5 t | 34.2 t | 34.3 t | 34.5 t | 33.3 t | 34.3 t | 34.3 t | 34.3 t | 34.2 t | 34.2 t | 34.1 t | 34.2 t |
| 16 | 34.1 t | 33.5 t | 34.1 t | 34.1 t | 33.6 t | 34.1 t | 31.7 t | 33.5 t | 33.5 t | 33.5 t | 33.0 t | 34.0 t | 34.0 t | 34.0 t |
| 17 | 88.9 s | 89.4 s | 89.6 s | 89.5 s | 89.3 s | 89.6 s | 87.9 s | 89.3 s | 89.3 s | 89.3 s | 89.5 s | 89.5 s | 89.4 s | 89.4 s |
| 18 | 9.8 q | 11.3 q | 11.3 q | 9.8 q | 11.2 q | 11.3 q | 11.1 q | 11.2 q | 11.2 q | 11.2 q | 10.9 q | 10.9 q | 10.9 q | 10.9 q |
| 19 | 18.7 q | 18.5 q | 18.5 q | 18.6 q | 18.5 q | 18.5 q | 18.2 q | 18.5 q | 18.9 q | 18.4 q | 18.7 q | 18.5 q | 18.5 q | 18.6 q |
| 20 | 76.3 d | 71.6 d | 76.4 d | 76.3 d | 71.7 d | 76.0 d | 74.6 d | 71.4 d | 71.6 d | 71.6 d | 75.5 d | 75.5 d | 75.3 d | 75.3 d |
| 21 | 15.2 q | 18.9 q | 15.2 q | 15.2 q | 18.7 q | 15.2 q | 15.5 q | 18.9 q | 18.5 q | 15.1 q | 15.2 q | 15.2 q | 15.2 q | 15.2 q |
| 1′ | 136.1 s | 131.9 s | 135.6 s | 136.1 s | 135.9 s | 132.2 s | 130.1 s | 169.1 s | 169.2 s | 169.2 s | 173.0 s | 173.0 s | 172.9 s | 172.9 s |
| 2′ | 129.1 d | 131.0 d | 129.3 d | 129.1 d | 129.4 d | 130.5 d | 129.6 d | 139.6 s | 139.4 s | 139.6 s | 22.1 q | 22.1 q | 22.1 q | 22.1 q |
| 3′ | 130.0 d | 129.5 d | 129.8 d | 130.0 d | 130.0 d | 129.2 d | 128.7 d | 130.1 d | 130.0 d | 130.1 d | ||||
| 4′ | 131.3 d | 134.3 d | 131.3 d | 131.3 d | 131.5 d | 133.7 d | 133.4 d | 14.5 q | 14.5 q | 14.5 q | ||||
| 5′ | 130.0 d | 129.5 d | 129.8 d | 130.0 d | 130.0 d | 129.2 d | 128.7 d | 12.1 q | 12.1 q | 12.1 q | ||||
| 6′ | 129.1 d | 131.0 d | 129.3 d | 129.1 d | 129.4 d | 130.5 d | 129.6 d | |||||||
| 7′ | 120.0 d | 167.8 s | 119.8 d | 119.9 d | 119.3 d | 167.8 s | 165.8 s | |||||||
| 8′ | 145.7 d | 145.3 d | 145.7 d | 146.8 d | ||||||||||
| 9′ | 167.7 s | 168.0 s | 167.7 s | 168.4 s | ||||||||||
| 1′′ | 97.2 d | 97.2 d | 131.7 s | 97.2 d | 97.2 d | 131.6 s | 96.1 d | 97.2 d | 97.2 d | 97.2 d | 168.5 s | 168.6 s | 168.5 s | 168.5 s |
| 2′′ | 35.9 t | 35.9 t | 131.0 d | 35.6 t | 35.6 t | 130.8 d | 34.5 t | 35.9 t | 36.7 t | 36.6 t | 139.5 s | 139.5 s | 139.4 s | 139.5 s |
| 3′′ | 79.2 d | 79.2 d | 129.5 d | 79.2 d | 79.2 d | 129.2 d | 77.4 d | 79.2 d | 78.5 d | 78.5 d | 130.0 d | 130.0 d | 129.9 d | 130.0 d |
| 4′′ | 74.5 d | 74.5 d | 134.2 d | 83.8 d | 83.8 d | 134.0 d | 82.5 d | 74.5 d | 83.9 d | 83.9 d | 14.5 q | 14.5 q | 14.5 q | 14.5 q |
| 5′′ | 71.4 d | 71.4 d | 129.5 d | 70.0 d | 70.0 d | 129.2 d | 68.5 d | 71.5 d | 70.0 d | 69.8 d | 12.2 q | 12.2 q | 12.2 q | 12.2 q |
| 6′′ | 18.6 q | 18.7 q | 131.0 d | 18.5 q | 18.5 q | 130.8 d | 18.2 q | 18.7 q | 18.5 q | 18.5 q | ||||
| 7′′ | 58.1 q | 58.1 q | 166.9 s | 58.4 q | 58.1 q | 166.6 s | 57.2 q | 58.1 q | 57.4 q | 57.6 q | ||||
| 1′′′ | 97.2 d | 101.2 d | 101.2 d | 97.2 d | 99.4 d | 102.8 d | 101.2 d | 97.2 d | 97.2 d | 97.2 d | 97.2 d | |||
| 2′′′ | 35.9 t | 36.7 t | 36.6 t | 35.6 t | 35.5 t | 37.4 t | 36.4 t | 35.9 t | 36.7 t | 36.6 t | 36.6 t | |||
| 3′′′ | 79.17 d | 78.6 d | 78.6 d | 79.2 d | 77.3 d | 81.6 d | 78.6 d | 79.2 d | 78.5 d | 79.1 d | 78.5 d | |||
| 4′′′ | 74.4 d | 74.5 d | 74.4 d | 83.8 d | 71.0 d | 77.0 d | 83.9 d | 74.7 d | 83.8 d | 83.8 d | 83.8 d | |||
| 5′′′ | 71.4 d | 71.3 d | 71.3 d | 70.0 d | 70.7 d | 73.3 d | 70.0 d | 71.4 d | 69.9 d | 69.9 d | 69.8 d | |||
| 6′′′ | 18.7 q | 18.7 q | 18.8 q | 18.5 q | 18.3 q | 18.4 q | 18.9 q | 18.4 q | 18.4 q | 18.5 q | 18.5 q | |||
| 7′′′ | 58.1 q | 59.3 q | 58.5 q | 58.1 q | 58.0 q | 58.5 q | 58.5 q | 58.1 q | 58.5 q | 58.1 q | 57.4 q | |||
| 1′′′′ | 101.2 d | 102.8 d | 102.8 d | 101.1 d | 101.2 d | |||||||||
| 2′′′′ | 36.6 t | 37.4 t | 37.4 t | 35.6 t | 36.4 t | |||||||||
| 3′′′′ | 78.6 d | 81.6 d | 81.6 d | 78.5 d | 78.54 d | |||||||||
| 4′′′′ | 74.4 d | 77.0 d | 77.0 d | 74.4 d | 83.8 d | |||||||||
| 5′′′′ | 71.3 d | 73.3 d | 73.3 d | 71.2 d | 69.9 d | |||||||||
| 6′′′′ | 18.7 q | 18.6 q | 18.4 q | 18.8 q | 18.5 q | |||||||||
| 7′′′′ | 58.4 q | 58.4 q | 57.4 q | 58.4 q | 58.5 q | |||||||||
| 1′′′′′ | 102.8 d | |||||||||||||
| 2′′′′′ | 37.4 t | |||||||||||||
| 3′′′′′ | 81.6 d | |||||||||||||
| 4′′′′′ | 76.9 d | |||||||||||||
| 5′′′′′ | 73.2 d | |||||||||||||
| 6′′′′′ | 18.4 q | |||||||||||||
| 7′′′′′ | 58.4 q |
Recorded at 125 MHz.
Recorded in methanol-d4.
Recorded in chloroform-d1.