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. 2021 Dec 22;12(1):498–508. doi: 10.1039/d1ra07498a

13C NMR data of compounds 1–14a.

No. 1b 2b 3b 4b 5b 6b 7c 8b 9b 10b 11b 12b 13b 14b
1 39.8 t 39.8 t 39.7 t 39.8 t 39.8 t 39.7 t 38.9 t 39.8 t 39.8 t 39.8 t 39.7 t 39.7 t 39.7 t 39.7 t
2 30.2 t 30.2 t 30.1 t 30.2 t 30.2 t 30.1 t 29.0 t 30.2 t 30.2 t 30.2 t 30.1 t 30.1 t 30.1 t 30.1 t
3 79.3 d 79.3 d 79.22 d 79.4 d 79.3 d 79.3 d 78.0 d 79.3 d 79.3 d 79.3 d 79.3 d 79.3 d 79.2 d 79.2 d
4 39.9 t 39.8 t 39.8 t 39.9 t 39.8 t 39.8 t 38.8 t 39.8 t 39.8 t 39.8 t 39.8 t 39.8 t 39.7 t 39.8 t
5 140.3 s 140.1 s 140.1 s 140.3 s 140.1 s 140.1 s 139.7 s 140.0 s 140.1 s 140.1 s 140.0 s 140.1 s 140.0 s 140.1 s
6 120.1 d 120.0 d 120.1 d 120.0 d 120.0 d 119.8 d 118.4 d 120.0 d 120.0 d 120.0 d 119.8 d 119.8 d 120.0 d 119.8 d
7 35.3 t 35.3 t 35.2 t 35.3 t 35.2 t 35.2 t 33.7 t 35.2 t 35.2 t 35.2 t 35.1 t 35.1 t 35.1 t 35.1 t
8 75.1 s 75.0 s 75.0 s 75.1 s 75.5 s 75.0 s 72.4 s 75.0 s 75.2 s 75.2 s 75.3 s 75.4 s 74.9 s 75.5 s
9 45.3 d 44.8 d 44.7 d 45.4 d 44.8 d 44.6 d 43.4 d 44.7 d 44.7 d 44.7 d 44.7 d 44.7 d 44.6 d 44.7 d
10 38.0 s 38.1 s 38.0 s 38.0 s 38.0 s 38.0 s 37.0 s 38.0 s 38.0 s 38.0 s 38.0 s 38.0 s 37.9 s 38.0 s
11 29.8 t 26.0 t 26.1 t 29.8 t 26.0 t 26.3 t 24.7 t 26.0 t 26.0 t 26.0 t 26.0 t 26.0 t 26.0 t 26.0 t
12 71.3 d 75.5 d 75.2 d 71.3 d 75.0 d 75.5 d 74.0 d 75.1 d 75.0 d 75.0 d 75.0 d 75.0 d 75.4 d 75.0 d
13 59.2 s 57.7 s 57.7 s 58.1 s 57.5 s 57.8 s 56.3 s 57.6 s 57.7 s 57.4 s 57.4 s 54.8 s 57.3 s 57.4 s
14 89.5 s 89.2 s 88.5 s 88.9 s 89.1 s 88.6 s 87.9 s 89.2 s 89.2 s 89.2 s 88.5 s 88.5 s 88.4 s 88.5 s
15 34.2 t 34.4 t 34.5 t 34.2 t 34.3 t 34.5 t 33.3 t 34.3 t 34.3 t 34.3 t 34.2 t 34.2 t 34.1 t 34.2 t
16 34.1 t 33.5 t 34.1 t 34.1 t 33.6 t 34.1 t 31.7 t 33.5 t 33.5 t 33.5 t 33.0 t 34.0 t 34.0 t 34.0 t
17 88.9 s 89.4 s 89.6 s 89.5 s 89.3 s 89.6 s 87.9 s 89.3 s 89.3 s 89.3 s 89.5 s 89.5 s 89.4 s 89.4 s
18 9.8 q 11.3 q 11.3 q 9.8 q 11.2 q 11.3 q 11.1 q 11.2 q 11.2 q 11.2 q 10.9 q 10.9 q 10.9 q 10.9 q
19 18.7 q 18.5 q 18.5 q 18.6 q 18.5 q 18.5 q 18.2 q 18.5 q 18.9 q 18.4 q 18.7 q 18.5 q 18.5 q 18.6 q
20 76.3 d 71.6 d 76.4 d 76.3 d 71.7 d 76.0 d 74.6 d 71.4 d 71.6 d 71.6 d 75.5 d 75.5 d 75.3 d 75.3 d
21 15.2 q 18.9 q 15.2 q 15.2 q 18.7 q 15.2 q 15.5 q 18.9 q 18.5 q 15.1 q 15.2 q 15.2 q 15.2 q 15.2 q
1′ 136.1 s 131.9 s 135.6 s 136.1 s 135.9 s 132.2 s 130.1 s 169.1 s 169.2 s 169.2 s 173.0 s 173.0 s 172.9 s 172.9 s
2′ 129.1 d 131.0 d 129.3 d 129.1 d 129.4 d 130.5 d 129.6 d 139.6 s 139.4 s 139.6 s 22.1 q 22.1 q 22.1 q 22.1 q
3′ 130.0 d 129.5 d 129.8 d 130.0 d 130.0 d 129.2 d 128.7 d 130.1 d 130.0 d 130.1 d
4′ 131.3 d 134.3 d 131.3 d 131.3 d 131.5 d 133.7 d 133.4 d 14.5 q 14.5 q 14.5 q
5′ 130.0 d 129.5 d 129.8 d 130.0 d 130.0 d 129.2 d 128.7 d 12.1 q 12.1 q 12.1 q
6′ 129.1 d 131.0 d 129.3 d 129.1 d 129.4 d 130.5 d 129.6 d
7′ 120.0 d 167.8 s 119.8 d 119.9 d 119.3 d 167.8 s 165.8 s
8′ 145.7 d 145.3 d 145.7 d 146.8 d
9′ 167.7 s 168.0 s 167.7 s 168.4 s
1′′ 97.2 d 97.2 d 131.7 s 97.2 d 97.2 d 131.6 s 96.1 d 97.2 d 97.2 d 97.2 d 168.5 s 168.6 s 168.5 s 168.5 s
2′′ 35.9 t 35.9 t 131.0 d 35.6 t 35.6 t 130.8 d 34.5 t 35.9 t 36.7 t 36.6 t 139.5 s 139.5 s 139.4 s 139.5 s
3′′ 79.2 d 79.2 d 129.5 d 79.2 d 79.2 d 129.2 d 77.4 d 79.2 d 78.5 d 78.5 d 130.0 d 130.0 d 129.9 d 130.0 d
4′′ 74.5 d 74.5 d 134.2 d 83.8 d 83.8 d 134.0 d 82.5 d 74.5 d 83.9 d 83.9 d 14.5 q 14.5 q 14.5 q 14.5 q
5′′ 71.4 d 71.4 d 129.5 d 70.0 d 70.0 d 129.2 d 68.5 d 71.5 d 70.0 d 69.8 d 12.2 q 12.2 q 12.2 q 12.2 q
6′′ 18.6 q 18.7 q 131.0 d 18.5 q 18.5 q 130.8 d 18.2 q 18.7 q 18.5 q 18.5 q
7′′ 58.1 q 58.1 q 166.9 s 58.4 q 58.1 q 166.6 s 57.2 q 58.1 q 57.4 q 57.6 q
1′′′ 97.2 d 101.2 d 101.2 d 97.2 d 99.4 d 102.8 d 101.2 d 97.2 d 97.2 d 97.2 d 97.2 d
2′′′ 35.9 t 36.7 t 36.6 t 35.6 t 35.5 t 37.4 t 36.4 t 35.9 t 36.7 t 36.6 t 36.6 t
3′′′ 79.17 d 78.6 d 78.6 d 79.2 d 77.3 d 81.6 d 78.6 d 79.2 d 78.5 d 79.1 d 78.5 d
4′′′ 74.4 d 74.5 d 74.4 d 83.8 d 71.0 d 77.0 d 83.9 d 74.7 d 83.8 d 83.8 d 83.8 d
5′′′ 71.4 d 71.3 d 71.3 d 70.0 d 70.7 d 73.3 d 70.0 d 71.4 d 69.9 d 69.9 d 69.8 d
6′′′ 18.7 q 18.7 q 18.8 q 18.5 q 18.3 q 18.4 q 18.9 q 18.4 q 18.4 q 18.5 q 18.5 q
7′′′ 58.1 q 59.3 q 58.5 q 58.1 q 58.0 q 58.5 q 58.5 q 58.1 q 58.5 q 58.1 q 57.4 q
1′′′′ 101.2 d 102.8 d 102.8 d 101.1 d 101.2 d
2′′′′ 36.6 t 37.4 t 37.4 t 35.6 t 36.4 t
3′′′′ 78.6 d 81.6 d 81.6 d 78.5 d 78.54 d
4′′′′ 74.4 d 77.0 d 77.0 d 74.4 d 83.8 d
5′′′′ 71.3 d 73.3 d 73.3 d 71.2 d 69.9 d
6′′′′ 18.7 q 18.6 q 18.4 q 18.8 q 18.5 q
7′′′′ 58.4 q 58.4 q 57.4 q 58.4 q 58.5 q
1′′′′′ 102.8 d
2′′′′′ 37.4 t
3′′′′′ 81.6 d
4′′′′′ 76.9 d
5′′′′′ 73.2 d
6′′′′′ 18.4 q
7′′′′′ 58.4 q
a

Recorded at 125 MHz.

b

Recorded in methanol-d4.

c

Recorded in chloroform-d1.