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. 2021 Jan 21;11(8):4339–4355. doi: 10.1039/d0ra09420j

Oxidation of alcohols to corresponding aldehydes or ketones in the present of Fe3O4@NFC@NNSM-Mn(iii) catalysta.

graphic file with name d0ra09420j-u34.jpg
Entry Substrate Product Time (min) Yieldb (%)
1 graphic file with name d0ra09420j-u35.jpg graphic file with name d0ra09420j-u36.jpg 20 97
2 graphic file with name d0ra09420j-u37.jpg graphic file with name d0ra09420j-u38.jpg 20 92
3 graphic file with name d0ra09420j-u39.jpg graphic file with name d0ra09420j-u40.jpg 15 90
4 graphic file with name d0ra09420j-u41.jpg graphic file with name d0ra09420j-u42.jpg 15 92
5 graphic file with name d0ra09420j-u43.jpg graphic file with name d0ra09420j-u44.jpg 30 88
6 graphic file with name d0ra09420j-u45.jpg graphic file with name d0ra09420j-u46.jpg 35 82
7 graphic file with name d0ra09420j-u47.jpg graphic file with name d0ra09420j-u48.jpg 45 80
8 graphic file with name d0ra09420j-u49.jpg graphic file with name d0ra09420j-u50.jpg 45 85
9 graphic file with name d0ra09420j-u51.jpg graphic file with name d0ra09420j-u52.jpg 35 95
10 graphic file with name d0ra09420j-u53.jpg graphic file with name d0ra09420j-u54.jpg 35 85
11 graphic file with name d0ra09420j-u55.jpg graphic file with name d0ra09420j-u56.jpg 30 90
12 graphic file with name d0ra09420j-u57.jpg graphic file with name d0ra09420j-u58.jpg 60 80
13 graphic file with name d0ra09420j-u59.jpg graphic file with name d0ra09420j-u60.jpg 30 95
14 graphic file with name d0ra09420j-u61.jpg graphic file with name d0ra09420j-u62.jpg 20 75
15 graphic file with name d0ra09420j-u63.jpg graphic file with name d0ra09420j-u64.jpg 15 97
a

Reaction conditions: alcohols (1 mmol), TBHP (2 mmol), catalyst (0.5 mol%), S. F., 40 °C.

b

Yields of product isolated.