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. 2021 Jan 22;11(8):4375–4394. doi: 10.1039/d0ra09287h

Assumptions regarding structure and heat transfer mechanisms and predictions made by a variety of thermal conductivity models42,43,47,48,106,113,116,122.

Assumptions References Conclusions References
Cells have a uniform size distribution 42, 43, 47, 106, 113 and 122 Conduction is the most significant mode of heat transfer 42, 43, 47, 48, 106 and 122
Considering only the average cell size is representative of the whole 42, 43, 47, 106, 113 and 122 Generally, reducing cell size reduces thermal conductivity 43, 47, 106, 113 and 122
Cells are generally spherical (isotropic) 42, 43, 47, 48, 106 and 122 Generally, increasing void fraction reduces thermal conductivity 42, 43, 47 and 116
Cells are closed 42, 43, 47, 48, 106, 113 and 122 Nanocellular foams display different trends than microcellular foams 47, 48 and 113
Convection is negligible 42, 43, 47, 48, 106, 113, 116 and 122 Impact radiation increases for high void fraction (low relative density) foams 42, 47 and 122
Radiation is ignored 48 Refractive index and absorption index have a significant impact on thermal conductivity 47 and 106
Reflectance and refraction index is constant for all cell sizes and void fractions 42, 43, 48, 106, 113, 116 and 122 Reflectance depends on cell size, void fraction, etc. 47
Consider only foam structure and primary material. No consideration for blends or additives 42, 43, 47, 48, 106, 113, 116 and 122 Width of cell size distribution is significant 48
Cell wall thickness remains essentially constant as cell size is changed 113 Changes in cell wall thickness and ratio of polymer present in cell walls to struts significantly impact thermal conductivity 113