Products and their yields in the C₆₀-promoted photoaddition reactions of benzylamines 1a–1c with DMAD under the oxygenated condition.

Entry	Amine	Irradiation time (min)	Conversiona (%)	Productb (%)
1	1a	10	100	2a (78)
2	1b	10	100	2b (73)
3	1c	10	93	2c (60), 3 (19)
4c	1a	30	—d	—d
5e	1a	30	—d	—d

^aConversion was determined based on recovered amine.

^bIsolation yields.

^cPhotoreaction in deoxygenated (using freeze–pump–thaw degassing) condition.

^dNo reaction.

^ePhotoreaction in the absence of C₆₀.