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. 2021 Feb 3;11(11):5914–5922. doi: 10.1039/d1ra00166c

Products and their yields in the C60-promoted photoaddition reactions of benzylamines 4a–4c and 5a–5c with DMAD under the oxygenated condition.

graphic file with name d1ra00166c-u2.jpg
Entry Amine Irradiation time (min) Conversiona (%) Productb (%)
1 4a 10 100 6a (65)
2 4b 10 100 6b (76)
3 4c 10 90 6c (60)
4 5a 10 34 7a (18)
5 5a 30 96 7a (51)
6 5b 10 39 7b (21)
7 5b 30 100 7b (53)
8 5c 10 11 7c (6)
9 5c 50 100 7c (53)
a

Conversion was determined based on recovered amine.

b

Isolation yields.