Products and their yields in the C60-promoted photoaddition reactions of benzylamines 4a–4c and 5a–5c with DMAD under the oxygenated condition.
| ||||
|---|---|---|---|---|
| Entry | Amine | Irradiation time (min) | Conversiona (%) | Productb (%) |
| 1 | 4a | 10 | 100 | 6a (65) |
| 2 | 4b | 10 | 100 | 6b (76) |
| 3 | 4c | 10 | 90 | 6c (60) |
| 4 | 5a | 10 | 34 | 7a (18) |
| 5 | 5a | 30 | 96 | 7a (51) |
| 6 | 5b | 10 | 39 | 7b (21) |
| 7 | 5b | 30 | 100 | 7b (53) |
| 8 | 5c | 10 | 11 | 7c (6) |
| 9 | 5c | 50 | 100 | 7c (53) |
Conversion was determined based on recovered amine.
Isolation yields.