Products and their yields in the C60-promoted photoaddition reactions of benzylamines 11–13 with DMAD under the oxygenated condition.
| |||
|---|---|---|---|
| Amine | Irradiation time (min) | Conversiona (%) | Productb (%) |
| 11 | 10 | 60 | 2a (15), 14 (22) |
| 11 | 20 | 100 | 2a (28), 14 (42) |
| 12 | 10 | 35 | 2c (14), 14 (9) |
| 12 | 20 | 79 | 2c (35), 14 (21) |
| 13 | 10 | 58 | 6a (16), 15 (15) |
| 13 | 20 | 100 | 6a (35), 15 (30) |
Conversion was determined based on recovered amine.
Isolation yields.