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. 2021 Feb 3;11(11):5914–5922. doi: 10.1039/d1ra00166c

Products and their yields in the visible light irradiated, C60-promoted photoaddition reactions of benzylamines 1a–1c with DMAD under the oxygenated condition.

graphic file with name d1ra00166c-u5.jpg
Amine Irradiation time (h) Conversiona (%) Productb (%)
1a 20 47 2a (32)
1a 40 100 2a (70)
1b 20 51 2b (36)
1b 40 100 2b (73)
1c 20 20 2c (10)
1c 40 48 2c (28)
1c 60 80 2c (45)
a

Conversion was determined based on recovered amine.

b

Isolation yields.