Products and their yields in the visible light irradiated, C60-promoted photoaddition reactions of benzylamines 1a–1c with DMAD under the oxygenated condition.
| |||
|---|---|---|---|
| Amine | Irradiation time (h) | Conversiona (%) | Productb (%) |
| 1a | 20 | 47 | 2a (32) |
| 1a | 40 | 100 | 2a (70) |
| 1b | 20 | 51 | 2b (36) |
| 1b | 40 | 100 | 2b (73) |
| 1c | 20 | 20 | 2c (10) |
| 1c | 40 | 48 | 2c (28) |
| 1c | 60 | 80 | 2c (45) |
Conversion was determined based on recovered amine.
Isolation yields.