Kinetic parameters for orthophosphate adsorption by hydrochars.
Kinetic parameters | pH 3 | pH 5 | pH 8 | |||||||
---|---|---|---|---|---|---|---|---|---|---|
HC | PRHC | POHC | HC | PRHC | POHC | HC | PRHC | POHC | ||
Pseudo-first order | R 2 | 0.7637 | 0.6899 | 0.5476 | 0.7122 | 0.6374 | 0.6256 | 0.8035 | 0.7291 | 0.6551 |
K 1 (min−1) | 0.0004 | 0.0004 | 0.0004 | 0.0004 | 0.0004 | 0.0006 | 0.0004 | 0.0004 | 0.0004 | |
Pseudo-second order | R 2 | 0.7489 | 0.7157 | 0.7049 | 0.7377 | 0.7126 | 0.7335 | 0.7506 | 0.7247 | 0.6961 |
K 2 (g mg−1 min−1) | 0.0610 | 0.0999 | 0.1031 | 0.0716 | 0.1137 | 0.1750 | 0.0480 | 0.0762 | 0.0970 | |
Elovich | R 2 | 0.7612 | 0.7488 | 0.7038 | 0.7456 | 0.7373 | 0.7038 | 0.7634 | 0.7591 | 0.7351 |
α (mg g−1 min−1) | 55.6626 | 68.9872 | 68.8631 | 59.4897 | 71.4767 | 80.7558 | 51.6533 | 62.1344 | 70.0282 | |
β (mg g−1) | 1.2116 | 1.0164 | 0.9705 | 1.1381 | 0.9649 | 0.8445 | 1.3152 | 1.1163 | 1.0134 | |
Intraparticle | R 2 | 0.7443 | 0.7372 | 0.6718 | 0.7295 | 0.7202 | 0.7365 | 0.7497 | 0.7422 | 0.7206 |
K i (mg g−1 h0.5) | 0.288 | 0.3892 | 0.3222 | 0.3106 | 0.3833 | 0.4146 | 0.2743 | 0.3373 | 0.3973 |