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. 2021 Feb 19;11(14):8218–8227. doi: 10.1039/d1ra00239b

Effect of addenda atom on conversion/TON/TOFa.

Catalyst Conversion (%)/TONb Time (h)/Conv%/TOF (h−1) Number of protons
Pd–PW12/ZrO2 15/4377 8/97/3538 3
Pd–PW11/ZrO2 96/28 010 2/96/14 005 7
a

Reaction conditions: cyclohexene (9.87 mmol), conc. of Pd (0.0034 mol%), substrate/catalyst ratio (29 177/1), H2O (50 mL), temp. (50 °C), H2 pressure (10 bar).

b

Time (2 h).