Physicochemical properties of selected porphyrin-based pigments12,16,17,19–21.
Pigmenta | Molecular formula | Molecular weight (g mol−1) | UV-vis absorption maxima (nm) | Color in solution | |
---|---|---|---|---|---|
Soret | Q-bands | ||||
Heme | C34H32FeN4O4 | 616.5 | 416b | 520, 550b | Red |
Hemin | C34H34ClFeN4O4 | 654.0 | 363, 385c | 550, 570c | Olive-green |
Hematin | C34H34FeN4O5 | 634.5 | 364, 383c | 613c | Dark blue-brown |
Biliverdin | C33H34N4O6 | 582.7 | 376c | 671c | Blue-green |
Bilirubin | C33H36N4O6 | 584.7 | 452c | — | Yellow-orange |
Protoporphyrin IX | C34H34N4O4 | 562.7 | 400d | 506, 532, 580, 630d | Red-brown |
Chlorophyll a | C55H72MgN4O5 | 893.5 | 430e | 662e | Yellow-green |
Chlorophyll b | C55H70MgN4O6 | 907.5 | 453e | 642e | Blue-green |
Chlorophyll c1 | C35H30MgN4O5 | 611.0 | 444e | 577, 626e | Blue-green |
Chlorophyll c2 | C35H28MgN4O5 | 609.0 | 447e | 580, 627e | Blue-green |
Chlorophyll c3 | C36H28MgN4O6 | 637.0 | 452e | 585, 627e | Blue-green |
Bacteriochlorophyll a | C55H74MgN4O6 | 911.5 | 388 | 805, 870 | Blue-green |
Measured in extracts of mitochondrial cytochrome c from a horse's heart.
Measured in 1 M phosphate-buffered saline (PBS) containing 30 mM NaOH (hemin), 7.2 mM KOH (bilirubin) or 5 mM KOH (biliverdin).
Measured in a mixture of acetonitrile and DMSO (3 : 1, v/v).
Measured in diethyl ether.