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. 2021 Feb 17;11(13):7552–7563. doi: 10.1039/d0ra10688g

Physicochemical properties of selected porphyrin-based pigments12,16,17,19–21.

Pigmenta Molecular formula Molecular weight (g mol−1) UV-vis absorption maxima (nm) Color in solution
Soret Q-bands
Heme C34H32FeN4O4 616.5 416b 520, 550b Red
Hemin C34H34ClFeN4O4 654.0 363, 385c 550, 570c Olive-green
Hematin C34H34FeN4O5 634.5 364, 383c 613c Dark blue-brown
Biliverdin C33H34N4O6 582.7 376c 671c Blue-green
Bilirubin C33H36N4O6 584.7 452c Yellow-orange
Protoporphyrin IX C34H34N4O4 562.7 400d 506, 532, 580, 630d Red-brown
Chlorophyll a C55H72MgN4O5 893.5 430e 662e Yellow-green
Chlorophyll b C55H70MgN4O6 907.5 453e 642e Blue-green
Chlorophyll c1 C35H30MgN4O5 611.0 444e 577, 626e Blue-green
Chlorophyll c2 C35H28MgN4O5 609.0 447e 580, 627e Blue-green
Chlorophyll c3 C36H28MgN4O6 637.0 452e 585, 627e Blue-green
Bacteriochlorophyll a C55H74MgN4O6 911.5 388 805, 870 Blue-green
a

For structures, see Fig. 2, 3, 6, and 7.

b

Measured in extracts of mitochondrial cytochrome c from a horse's heart.

c

Measured in 1 M phosphate-buffered saline (PBS) containing 30 mM NaOH (hemin), 7.2 mM KOH (bilirubin) or 5 mM KOH (biliverdin).

d

Measured in a mixture of acetonitrile and DMSO (3 : 1, v/v).

e

Measured in diethyl ether.