Hydrogen bond and intermolecular interaction geometries (Å, °) for compound 1^a.

1
D–H⋯A	D–H	H⋯A	D⋯A	∠D–H⋯A
N00I–H00I⋯Cl1Ai	0.860	2.20	3.03 (1)	163.0
N00D–H00D⋯Cl1Ai	0.860	2.32	3.12 (1)	154.7
N00H–H00H⋯Cl0Ai	0.860	2.210	3.053 (9)	166.7
N00H–H00H⋯Cl06i	0.860	2.205	3.057 (3)	170.7
N00J–H00J⋯Cl1	0.860	2.654	3.161 (4)	119.0
N00J–H00J⋯Cl01	0.860	2.114	2.948 (4)	163.3
N00J–H00J⋯Cl3	0.860	2.295	3.037 (4)	144.5
N00E–H00E⋯Cl1	0.860	2.443	3.194 (4)	146.2
N00G–H00G⋯Cl1	0.860	2.085	2.912 (4)	161.1
N00K–H00K⋯Cl1Aii	0.860	2.59	3.22 (1)	131.2
N00K–H00K⋯Cl2Aii	0.860	2.30	3.11 (1)	156.1
N00K–H00K⋯Cl05ii	0.860	2.346	3.153 (2)	156.4
N00F–H00F⋯Cl2	0.860	2.036	2.880 (4)	166.7
N00F–H00F⋯Cl4	0.860	2.216	3.057 (5)	165.8
C00L–H00L⋯Cl01iii	0.950	2.793	3.482 (5)	130.2
C00N–H00N⋯Cl05iv	0.950	2.80	3.52 (1)	133.3
C01D–H01D⋯Cl07v	0.950	2.498	3.357 (5)	150.2
C01D–H01D⋯Cl08v	0.950	2.78	3.49 (1)	131.9
C01F–H01F⋯Cl10ii	0.950	2.566	3.38 (1)	144.0
C01F⋯C01Dv	—	—	3.253 (6)	—
C01E–H01E⋯π*	—	2.892	—	140.87
C01A–H01A⋯π*	—	2.929	—	125.2
C015–H015⋯π*	—	3.184	—	131.80
C015–H015⋯π*	—	3.224	—	138.1
C016–H016⋯π*	—	3.215	—	130.59
C016–H016⋯π*	—	3.267	—	121.61
π⋯π*	—	—	3.585	—
π⋯π*	—	—	3.619	—

^aSymmetry transformations used to generate equivalent atoms for 1: (i) , , ; (ii) , , ; (iii) , , ; (iv) x − 1, y + 1, z; (v) , , ; *for π⋯π interactions d(D⋯A) = Cg⋯Cg and for C–H⋯π interactions d(H⋯A) = H⋯Cg, where Cg = centroid of the aromatic pyridine rings.