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. 2021 Mar 4;11(16):9600–9607. doi: 10.1039/d1ra00837d

The resonance parameters of the tunneling-predissociation levels with the rotation quantum number J = 0. WKB method has been employed to calculate the resonance parameters for states ν = 1–4 of 33Σ, and to be more accurately, the scattering method is used for 33Σ states with ν = 5, 6 and the 23Π states.

ν Position (eV) Width (cm−1) Lifetime (s)
3 3 Σ
0 2.45297 1.396 × 10−23 1.521 × 1012
1 2.52746 7.850 × 10−18 2.706 × 106
2 2.59519 5.964 × 10−13 3.560 × 101
3 2.6558 8.742 × 10−9 2.430 × 10−3
4 2.7089 2.820 × 10−5 7.530 × 10−7
5 2.75408 8.470 × 10−3 1.254 × 10−9
6 2.79094 1.164 × 100 9.117 × 10−12
2 3 Π
0 4.5129 4.566 × 100 2.325 × 10−12