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. 2021 Mar 1;11(16):9130–9221. doi: 10.1039/d0ra09759d

Preparation of sodium arylsulfinates by the reaction of Mg or BuLi reagents with DABSO (11).

graphic file with name d0ra09759d-u1.jpg
Sodium arylsulfinates Method-A Method-B
graphic file with name d0ra09759d-u2.jpg R = H: 72% R = H: 85%
R = 4-Ph: 87% R = 4-Ph: 42%
R = 4-CF3: 91% R = 4-CF3: 48%
R = 2-CF3: 75% R = 2-CF3: 99%
R = 4-OMe: 48% R = 4-OMe: 59%
R = 3-OMe: 85% R = 3-OMe: 91%
graphic file with name d0ra09759d-u3.jpg 48% 82%
graphic file with name d0ra09759d-u4.jpg 69% 64%