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. 2021 Mar 1;11(16):9130–9221. doi: 10.1039/d0ra09759d

C3-sulfenylation of indoles with sodium sulfinates.

graphic file with name d0ra09759d-u36.jpg
Thioethers A or B Thioethers A or B
graphic file with name d0ra09759d-u37.jpg A: 85% graphic file with name d0ra09759d-u38.jpg Ar = 4-MeC6H4, A: 90%; B: 85%
B: 75% Ar = 4-ClC6H4, A: 93%; B: 97%
graphic file with name d0ra09759d-u39.jpg A: 65% graphic file with name d0ra09759d-u40.jpg Ar = C6H5, A: 90%
B: 44% Ar = 4-MeC6H4, B: 88%
graphic file with name d0ra09759d-u41.jpg Ar = C6H5, A: 82% graphic file with name d0ra09759d-u42.jpg Ar = C6H5, A: 86%
Ar = 4-MeC6H4, B: 88% Ar = 4-MeC6H4, B: 83%
graphic file with name d0ra09759d-u43.jpg Ar = C6H5, A: 87% graphic file with name d0ra09759d-u44.jpg Ar = C6H5, A: 0%
Ar = 4-MeC6H4, B: 89% Ar = 4-MeC6H4, B: 75%