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. 2021 Mar 12;11(18):10727–10737. doi: 10.1039/d1ra00690h

All results for combustion experiments at T = 298.15 K (p° = 0.1 MPa) of the methoxy substituted benzenesa.

1,2,3-Tri-methoxy-benzene (cr) 1,2,4-Tri-methoxy-benzene (liq) 3,4,5-Tri-methoxy-toluene (liq)
28 633.2 28 640.8 30 018.3
28 617.4 28 649.1 30 020.6
28 631.6 28 631.5 30 002.9
28 620.0 28 640.3 30 014.5
28 610.2 28 621.4 30 025.5
30 034.9
Δcu°(cr or liq)/(J g−1)a −28622.5 ± 4.4 −28636.6 ± 4.7 −30019.5 ± 4.4
ΔcHom(cr or liq)/(kJ mol−1)b −4817.7 ± 1.8 −4820.1 ± 1.9 −5475.0 ± 2.0
ΔfHom(cr or liq)/(kJ mol−1)b −438.9 ± 2.1 −436.5 ± 2.2 −460.9 ± 2.4
a

Uncertainty of combustion energy is expressed as standard deviation of the mean.

b

Uncertainties are expressed as the twice standard deviation of the mean.