Relative energies (in kcal mol−1) of the stationary points in the hydrohydrazination of the substituted phenylacetylene with parent hydrazine.
| Trifluoromethyl | Methoxy | |
|---|---|---|
| R | 0.0 | 0.0 |
| TS1 | 25.7 | 30.7 |
| IM | −39.2 | −36.9 |
| TS2 | 10.9 | 13.7 |
| P | −45.4 | −41.6 |
| Trifluoromethyl | Methoxy | |
|---|---|---|
| R | 0.0 | 0.0 |
| TS1 | 25.7 | 30.7 |
| IM | −39.2 | −36.9 |
| TS2 | 10.9 | 13.7 |
| P | −45.4 | −41.6 |