Photophysical data for DSB derivatives in different solvents.
| Solvent | λ ab (nm) | λ em (nm) | Stock shifts (cm−1) | ε (L mol−1 cm−1) | E (eV) |
|---|---|---|---|---|---|
| 8a M | |||||
| DMF | 355 | 540 | 9650 | 96 836 | 3.49 |
| CHCl3 | 355 | 552 | 10 053 | 73 757 | 3.49 |
| THF | 355 | 529 | 9265 | 94 671 | 3.49 |
| Dioxane | 355 | 509 | 8522 | 122904 | 3.49 |
| Toluene | 355 | 507 | 8445 | 88 301 | 3.49 |
| 8b P | |||||
| DMF | 355 | 532 | 9372 | 60 756 | 3.49 |
| CHCl3 | 345 | 535 | 10 293 | 53 302 | 3.59 |
| THF | 352 | 524 | 9325 | 67 162 | 3.52 |
| Dioxane | 352 | 506 | 8646 | 62 334 | 3.52 |
| Toluene | 350 | 501 | 8611 | 64 526 | 3.54 |
| 8c Z | |||||
| DMF | 342 | 532 | 10 442 | 52 370 | 3.62 |
| CHCl3 | 340 | 545 | 11 063 | 65 654 | 3.65 |
| THF | 340 | 527 | 10 436 | 69 341 | 3.65 |
| Dioxane | 340 | 511 | 9842 | 56 285 | 3.65 |
| Toluene | 340 | 508 | 9726 | 65 293 | 3.65 |
| 8d I | |||||
| DMF | 330 | 533 | 11 541 | 97 190 | 3.75 |
| CHCl3 | 330 | 557 | 12 349 | 80 833 | 3.75 |
| THF | 330 | 530 | 11 435 | 87 939 | 3.75 |
| Dioxane | 328 | 504 | 10 646 | 98 910 | 3.78 |
| Toluene | 330 | 496 | 10 141 | 85 460 | 3.75 |
| 8e A | |||||
| DMF | 350 | 541 | 10 087 | 45 461 | 3.54 |
| CHCl3 | 345 | 550 | 10 803 | 39 392 | 3.59 |
| THF | 345 | 529 | 10 081 | 49 873 | 3.59 |
| Dioxane | 345 | 509 | 9339 | 53 013 | 3.59 |
| Toluene | 345 | 507 | 9261 | 55 189 | 3.59 |