Nano-MgFe2O4/Cu-catalysed reaction of styrene episulfide with phenylacetylene and sodium azide under different conditionsa.
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|---|---|---|---|---|---|
| Entry | MgFe2O4/Cu (g) | Solvent | Time (h) | Temperature (°C) | Yieldb (%) |
| 1 | — | H2O | 11 | 60 | 0 |
| 2 | 0.005 | H2O | 5 | 60 | 40 |
| 3 | 0.01 | H2O | 5 | 60 | 75 |
| 4 | 0.02 | H 2 O | 2.5 | 60 | 96 |
| 5 | 0.03 | H2O | 2.4 | 60 | 96 |
| 6 | 0.02 | CH3CN | 3 | 82 | 50 |
| 7 | 0.02 | EtOH | 3 | 78 | 60 |
| 8 | 0.02 | MeOH | 3 | 65 | 60 |
| 9 | 0.02 | EtOAc | 3 | 77 | 65 |
| 10 | 0.02 | DMF | 3 | 100 | 55 |
| 11 | 0.02 | THF | 20 | 60 | 0 |
| 12 | 0.02 | n-Hexane | 20 | 68 | 0 |
| 13 | 0.02 | CCl4 | 20 | 77 | 0 |
| 14 | 0.02 | H2O | 10 | 25 | 45 |
| 15 | 0.02 | H2O | 6 | 45 | 70 |
| 16c | 0.02 | H2O | 4 | 60 | Trace |
| 17d | 0.02 | H2O | 3 | 60 | 92 |
All reactions were carried out with styrene episulfide (1 mmol), phenylacetylene (1 mmol) and sodium azide (1.2 mmol).
Isolated yields.
Catalysed by MgFe2O4.
Catalysed by Cu nanoparticles.