Effect of the PVC membrane composition on the performance characteristics of the prepared sensorsb.
Sensor | Composition | Performance | |||
---|---|---|---|---|---|
Plasticizer | Ion exchanger | Linearity range (M) | Slopea (mV per decade) | r a | |
1 | TCP | TPB | 1.58 × 10−5 to 3.85 × 10−3 | 34.92 | 0.9713 |
2 | TCP | PM | 1.58 × 10−5 to 3.85 × 10−3 | 30.96 | 0.9907 |
3 | TCP | AR | 1.58 × 10−5 to 3.85 × 10−3 | 49.83 | 0.9879 |
4 | TCP | PT | 1.58 × 10−5 to 1.00 × 10−2 | 57.67 | 0.9965 |
5 | DBP | PT | 4.75 × 10−5 to 3.85 × 10−3 | 35.42 | 0.9793 |
6 | DOP | PT | 5.87 × 10−7 to 1.28 × 10−3 | 15.95 | 0.9918 |
7 | NPPE | PT | 5.87 × 10−7 to 4.28 × 10−4 | 10.56 | 0.9921 |
8 | NPOE | PT | 1.96 × 10−7 to 3.85 × 10−3 | 4.34 | 0.9339 |
Average of three determinations.
Tricresyl phosphate (TCP), tungstophosphoric acid hydrate (PT), sodium tetraphenyl borate (TPB), 12-molybdophosphoric acid (PM), ammonium reineckate (AR), dibutyl phthalate (DBP), dioctyl phthalate (DOP), 2-nitrophenyl phenyl ether (NPPE), 2-nitrophenyl octyl ether (NPOE).