Effect of ionophore types and conditioning time on the performance of the prepared sensorsb.
Sensor | Parameter | Performance | |||
---|---|---|---|---|---|
Ionophore | Conditioning time | Linearity range (M) | Slopea (mV per decade) | r a | |
9 | CX-4 | One hour | 3.79 × 10−5 to 1.00 × 10−2 | 27.46 | 0.9549 |
CX-4 | Overnight | 1.80 × 10−5 to 1.00 × 10−2 | 31.77 | 0.9810 | |
10 | CX-6 | One hour | 6.00 × 10−6 to 1.00 × 10−2 | 44.62 | 0.9539 |
CX-6 | Overnight | 6.00×10−6 to 2.86 × 10−3 | 53.43 | 0.9802 | |
11 | CX-8 | One hour | 6.00 × 10−6 to 1.00 × 10−2 | 58.86 | 0.9985 |
CX-8 | Overnight | 6.00 × 10−6 to 1.00 × 10−2 | 56.59 | 0.9903 | |
12 | β-CD | One hour | 6.00×10−6 to 1.00 × 10−2 | 56.34 | 0.9778 |
β-CD | Overnight | 6.00 × 10−6 to 1.00 × 10−2 | 58.69 | 0.9919 | |
13 | CX-8 : β-CD (1 : 1) | One hour | 6.00 × 10−6 to 1.00 × 10−2 | 52.56 | 0.9910 |
Average of three determinations.
Calix[4]arene-25,26,27,28-tetrol (CX-4), calix[6]arene (CX-6), calix[8]arene (CX-8), β-cyclodextrin (β-CD).