Activation energy and thermodynamic parameters during the pyrolysis process of MIW under the heating rate of 30 °C min⁻¹.

α	DAE method							Starink method
	E α, kJ mol−1	A α , min−1	k, min−1	ΔHα, kJ mol−1	Energy barrier, kJ mol−1	ΔGα, kJ mol−1	ΔSα, J mol−1 K−1	E α, kJ mol−1	A α , min−1	k, min−1	ΔHα, kJ mol−1	Energy barrier, kJ mol−1	ΔGα, kJ mol−1	ΔSα, J mol−1 K−1
0.05	149.54	8.8 × 1012	0.05	144.98	4.56	151.43	−10.57	150.33	1.0 × 1013	0.05	145.77	4.56	151.40	−9.23
0.1	143.03	2.3 × 1012	0.15	138.32	4.71	151.66	−21.83	143.84	2.8 × 1012	0.15	139.13	4.71	151.63	−20.45
0.15	145.43	3.8 × 1012	0.25	140.64	4.79	151.57	−17.90	146.25	4.5 × 1012	0.25	141.46	4.79	151.54	−16.51
0.2	144.20	3.0 × 1012	0.38	139.34	4.86	151.62	−20.09	145.04	3.5 × 1012	0.38	140.18	4.86	151.59	−18.66
0.25	153.03	1.8 × 1013	0.56	148.11	4.92	151.31	−5.25	153.88	2.1 × 1013	0.56	148.96	4.92	151.29	−3.81
0.3	160.68	8.5 × 1013	0.83	155.70	4.98	151.07	7.58	161.53	1.0 × 1014	0.83	156.55	4.98	151.04	9.02
0.35	168.79	4.4 × 1014	1.26	163.75	5.04	150.82	21.17	169.65	5.2 × 1014	1.27	164.61	5.04	150.79	22.62
0.4	175.59	1.7 × 1015	1.72	170.51	5.08	150.62	32.56	176.46	2.1 × 1015	1.73	171.38	5.08	150.59	34.02
0.45	170.17	5.8 × 1014	2.28	165.04	5.13	150.77	23.35	171.05	7.0 × 1014	2.30	165.92	5.13	150.75	24.83
0.5	160.78	8.7 × 1013	2.88	155.60	5.18	151.06	7.42	161.68	1.0 × 1014	2.91	156.50	5.18	151.03	8.94
0.55	151.72	1.4 × 1013	3.96	146.47	5.25	151.36	−8.01	152.64	1.7 × 1013	4.01	147.39	5.25	151.33	−6.45
0.6	144.99	3.5 × 1012	6.05	139.64	5.35	151.59	−19.56	145.93	4.2 × 1012	6.15	140.58	5.35	151.56	−17.97
0.65	143.03	2.3 × 1012	9.95	137.57	5.46	151.66	−23.06	144.00	2.8 × 1012	10.15	138.54	5.46	151.63	−21.42
0.7	157.04	4.0 × 1013	24.32	151.46	5.58	151.18	0.45	158.02	4.9 × 1013	24.90	152.44	5.58	151.15	2.11