Values of hopping lengths (LA and LB), ionic radii, the tetrahedral and octahedral bond lengths (dAE) and (dBE), tetrahedral edge (dAL), shared and unshared octahedral edge (dBL) and (dBEU), inter-atomic bond lengths and angles for Ni0.6Zn0.4Al0.5Fe1.5−xNdxO4 (x = 0.0, 0.05, 0.075 and 0.1) nanoparticle samples.
Parameter | x = 0.0 | x = 0.05 | x = 0.075 | x = 0.1 |
---|---|---|---|---|
L A (Å) | 3.614 | 3.616 | 3.615 | 3.617 |
L B (Å) | 2.951 | 2.952 | 2.952 | 2.953 |
r A (Å) | 0.6492 | 0.6492 | 0.6492 | 0.6492 |
r B (Å) | 0.6429 | 0.6525 | 0.6568 | 0.7152 |
U (Å) | 0.3875 | 0.3874 | 0.3873 | 0.3872 |
d AE (Å) | 3.247 | 3.237 | 3.236 | 3.236 |
d BE (Å) | 2.639 | 2.653 | 2.656 | 2.660 |
d AL (Å) | 1.998 | 1.982 | 1.982 | 1.981 |
d BL (Å) | 1.979 | 1.984 | 1.986 | 1.988 |
d BEU (Å) | 2.951 | 2.952 | 2.953 | 2.955 |
p (Å) | 1.973 | 1.979 | 1.981 | 1.983 |
q (Å) | 1.988 | 1.982 | 1.982 | 1.981 |
r (Å) | 3.807 | 3.796 | 3.795 | 3.794 |
s (Å) | 3.666 | 3.667 | 3.668 | 3.669 |
b (Å) | 2.943 | 2.945 | 2.946 | 2.948 |
c (Å) | 3.451 | 3.453 | 3.455 | 3457 |
d (Å) | 3.604 | 3.607 | 3.609 | 3.610 |
e (Å) | 5.407 | 5.411 | 5.413 | 5.416 |
f (Å) | 5.098 | 5.101 | 5.104 | 5.106 |
θ 1 (°) | 121.16 | 121.32 | 121.34 | 121.40 |
θ 2 (°) | 136.18 | 136.71 | 136.85 | 137.00 |
θ 3 (°) | 127.72 | 127.39 | 127.28 | 127.23 |
θ 4 (°) | 126.68 | 126.61 | 126.63 | 126.60 |
θ 5 (°) | 68.87 | 69.26 | 69.34 | 69.40 |