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. 2021 Apr 16;11(24):14453–14458. doi: 10.1039/d1ra01980e

Transesterification reactions of 1 and 2 with MeOH promoted by TMSBr.

graphic file with name d1ra01980e-u1.jpg
Entry Oil TMSBr/oila MeOH/oila T (°C) t (h) FAMEb (%)
1 1 2.2 4.5 60 8 12
2 1 2.2–6.6 4.5–9 60 30 28
3 1 2.2–4.4 4.5 100 60 42
4 1 2.2 4.5 100 72 60
5 2 3 4.5–35 60 8 + 6 90
6 2 3 4.5–35 60 12 + 6 93
a

Molar ratio.

b

Determined via1H NMR analyses.