Thermodynamic parameters for the adsorption of (H1, H2 and H3) derivatives on the C-steel surface in 1 M HCl at different temperatures.
Comp. | Temp., °C | K ads, M−1 | , kJ mol−1 | , kJ mol−1 | , J mol−1 K−1 |
---|---|---|---|---|---|
H1 | 25 | 5.67 | 14.25 | 48.8 | 169 |
30 | 6.29 | 14.75 | |||
35 | 8.21 | 15.68 | |||
40 | 11.33 | 16.77 | |||
45 | 20.03 | 18.55 | |||
H2 | 25 | 5.38 | 14.12 | 40.3 | 188 |
30 | 5.90 | 14.59 | |||
35 | 7.45 | 15.43 | |||
40 | 9.80 | 16.39 | |||
45 | 15.52 | 17.87 | |||
H3 | 25 | 5.67 | 14.25 | 48.8 | 212 |
30 | 6.29 | 14.75 | |||
35 | 8.21 | 15.68 | |||
40 | 11.33 | 16.77 | |||
45 | 20.03 | 18.55 |