Electrochemical kinetic parameters obtained from the EIS technique for the corrosion of C-steel in 1 M HCl without and with various concentrations of investigated compounds at 25 °C.
C. | Conc., M | R p, Ω cm2 | C dl, μF cm−2 | θ | % IE |
---|---|---|---|---|---|
Blank | 77.72 | 105.25 ± 1.731 | |||
H1 | 1 × 10−6 | 147.2 | 94.76 ± 1.734 | 0.472 | 47.2 |
2 × 10−6 | 164.5 | 89.91 ± 1.742 | 0.528 | 52.8 | |
5 × 10−6 | 282.8 | 55.65 ± 2.333 | 0.725 | 72.5 | |
10 × 10−6 | 316.9 | 53.40 ± 2.603 | 0.755 | 75.47 | |
15 × 10−6 | 338.5 | 52.17 ± 2.309 | 0.770 | 77.0 | |
20 × 10−6 | 654 | 42.98 ± 1.201 | 0.881 | 88.1 | |
H2 | 1 × 10−6 | 143.2 | 88.59 ± 1.452 | 0.457 | 45.7 |
2 × 10−6 | 155.7 | 85.05 ± 1.732 | 0.501 | 50.1 | |
5 × 10−6 | 155.7 | 74.28 ± 2.024 | 0.501 | 50.1 | |
10 × 10−6 | 155.9 | 69.95 ± 2.021 | 0.502 | 50.2 | |
15 × 10−6 | 298.8 | 64.75 ± 2.022 | 0.740 | 74.0 | |
20 × 10−6 | 354.3 | 51.20 ± 1.732 | 0.781 | 78.1 | |
H3 | 1 × 10−6 | 123.1 | 79.40 ± 2.027 | 0.369 | 36.9 |
2 × 10−6 | 148.2 | 72.31 ± 2.33 | 0.476 | 47.6 | |
5 × 10−6 | 286.3 | 56.45 ± 2.34 | 0.729 | 72.9 | |
10 × 10−6 | 317.1 | 51.22 ± 1.45 | 0.755 | 75.5 | |
15 × 10−6 | 338.5 | 48.11 ± 2.027 | 0.770 | 77.0 | |
20 × 10−6 | 653.1 | 43.19 ± 3.179 | 0.881 | 88.1 |