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Fig. 1. The scope of thiols and benzyl alcohols. a The standard reaction conditions; isolated yields are provided (average of 2 independent runs). b 2-Phenylpropan-2-ol 1 (2.4 equiv.). c Cu(OTf)2 (8 mol%), DCE instead of DCM, 40 °C. d Cu(OTf)2 (8 mol%), DCE instead of DCM, 80 °C.