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. 2021 Feb 23;11(14):8356–8361. doi: 10.1039/d1ra00236h

Scope of tetrahydrocarbazole deuterationa.

graphic file with name d1ra00236h-u6.jpg
graphic file with name d1ra00236h-u7.jpg
a

1u (0.1 mmol, 1 equiv.), [Cp*RhCl2]2 (5 mol%), AgNTf2 (20 mol%), Cu(OAc)2 (3 equiv.), D2O (0.5 mL), 80 °C, 12 h.

b

Deuterium incorporation at the aromatic position was determined by 1H NMR spectroscopy.

c

Data are reported as isolated yields.