Scope of tetrahydrocarbazole deuterationa.
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1u (0.1 mmol, 1 equiv.), [Cp*RhCl2]2 (5 mol%), AgNTf2 (20 mol%), Cu(OAc)2 (3 equiv.), D2O (0.5 mL), 80 °C, 12 h.
Deuterium incorporation at the aromatic position was determined by 1H NMR spectroscopy.
Data are reported as isolated yields.