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. 2021 Apr 21;11(25):14941–14955. doi: 10.1039/d0ra06872a

Scheme 13. (a) Photoredox-mediated synthesis of (1-chloro-3,3,3-trifluoropropyl)benzenes 21 by reaction between styrene derivatives 20, Umemoto's reagent 4, and TMSCl; (b) Cu-catalyzed synthesis of β-CF3 benzyl chlorides 23via a three-component reaction between styrenes 22, TfNHNHBoc, and NaCl.

Scheme 13