Table 31.
The 13C-NMR spectral data of compounds 111–122 except which has no reported 13C-NMR data.
| C | 111 | 112 | 113 | 114 | 115 | 116 | 117 | 119 | 120 | 121 | 122 |
|---|---|---|---|---|---|---|---|---|---|---|---|
| 2 | 167.2 | 167.6 | 169.7 | 160.3 | 163.0 | 160.1 | 163.1 | 160.6 | 164.0 | 167.6 | 166.8 |
| 3 | 112.1 | 112.2 | 110.5 | 1125 | 113.8 | 112.5 | 111.0 | 112.5 | 112.4 | 112.2 | 112.2 |
| 4 | 182.2 | 182.3 | 182.4 | 178.6 | 182.1 | 178.4 | 181.8 | 178.6 | 182.0 | 182.3 | 182.3 |
| 5 | 143.5 | 144.6 | 144.8 | 141.0 | 144.7 | 140.4 | 146.1 | 141.8 | 144.9 | 144.6 | 144.8 |
| 6 | 116.3 | 112.6 | 112.7 | 115.8 | 112.2 | 115.7 | 128.3 | 111.5 | 113.1 | 112.6 | 112.7 |
| 7 | 161.3 | 162.0 | 162.1 | 159.l | 162.1 | 159.4 | 161.1 | 159.7 | 162.3 | 161.0 | 162.2 |
| 8 | 110.0 | 111.9 | 111.8 | 110.2 | 112.0 | 110.7 | 121.1 | 110.8 | 111.6 | 111.9 | 111.9 |
| 9 | 160.4 | 159.6 | 159.4 | 158.3 | 159.6 | 157.9 | 157.9 | 157.4 | 159.5 | 159.6 | 159.6 |
| 10 | 117.0 | 117.3 | 117.5 | 114.8 | 117.1 | 114.8 | 114.3 | 115.6 | 117.6 | 117.2 | 117.3 |
| 11 | 44.3 | 44.6 | 75.7 | 48.1 | 49.1 | 47.8 | 48.5 | 47.9 | 98.6 | 44.6 | 44.6 |
| 12 | 66.7 | 66.8 | 69.2 | 202.4 | 204.7 | 202.3 | 204.6 | 202.1 | 203.7 | 66.8 | 66.8 |
| 13 | 23.5 | 23.6 | 19.7 | 30.4 | 29.9 | 29.6 | 30.7 | 29.6 | 23.7 | 23.7 | 24.0 |
| 14 | 23.5 | 23.6 | 23.7 | 22.7 | 23.7 | 22.6 | 23.3 | 22.7 | 25.0 | 23.6 | 23.5 |
| 15 | - | 57.1 | 57.1 | - | 57.1 | - | 55.8 | 55.5 | 57.2 | 57.1 | 57.1 |
| 1′ | 73.0 | 72.1 | 72.8 | 70.2 | 72.1 | 73.3 | 75.6 | 70.4 | 72.6 | 72.6 | 72.6 |
| 2′ | 74.0 | 74.0 | 74.1 | 72.3 | 73.9 | 70.8 | 72.3 | 72.2 | 74.3 | 74.1 | 73.6 |
| 3′ | 77.9 | 77.9 | 77.8 | 76.0 | 77.9 | 78.5 | 79.9 | 75.8 | 78.0 | 77.8 | 77.6 |
| 4′ | 72.1 | 72.7 | 72.3 | 70.2 | 72.6 | 70.4 | 72.1 | 70.6 | 71.9 | 78.3 | 78.1 |
| 5′ | 82.8 | 82.9 | 83.0 | 81.8 | 82.8 | 78.4 | 78.5 | 81.9 | 83.3 | 82.9 | 82.9 |
| 6′ | 63.1 | 63.1 | 63.1 | 61.8 | 63.3 | 64.8 | 65.4 | 61.5 | 63.5 | 63.0 | 63.0 |
| 1″ | 128.3 | 127.5 | 135.7 | 125 I | 127.0 | 125.0 | 128.3 | 125.5 | 135.7 | 129.8 | 129.7 |
| 2″ | 131.0 | 115.1 | 129.2 | 1301 | 130.8 | 130.3 | 131.0 | 111.1 | 129.3 | 130.8 | 132.6 |
| 3″ | 116.7 | 149.9 | 130.1 | 115.8 | 116.7 | 115.7 | 115.3 | 147.9 | 130.1 | 118.0 | 116.7 |
| 4″ | 161.2 | 146.6 | 131.6 | 159.6 | 161.3 | 159.7 | 160.4 | 149.2 | 131.6 | 163.8 | 159.7 |
| 5″ | 116.7 | 116.6 | 130.1 | 115.8 | 116.7 | 115.7 | 115.3 | 115.5 | 130.1 | - | - |
| 6″ | 131.0 | 123.0 | 129.2 | 1301 | 130.8 | 130.3 | 131.0 | 122.9 | 129.3 | - | - |
| 7″ | 146.2 | 147.1 | 146.4 | 144.4 | 145.3 | 144.9 | 146.2 | 144.6 | 146.3 | 146.0 | 144.7 |
| 8″ | 115.8 | 114.5 | 118.4 | 114.1 | 115.1 | 114.0 | 116.0 | 114.2 | 118.5 | 116.5 | 117.6 |
| 9″ | 168.0 | 168.2 | 167.4 | 165.4 | 168.1 | 166.7 | 169.1 | 165.4 | 167.4 | 167.8 | 167.7 |
| OCH3 | 56.1 | - | - | - | - | - | - | 56.3 | - | - | - |
| 1‴ | - | - | - | - | - | - | - | - | - | 101.9 | 101.7 |
| 2‴ | - | - | - | - | - | - | - | - | - | 74.8 | 74.9 |
| 3‴ | - | - | - | - | - | - | - | - | - | 72.1 | 72.6 |
| 4‴ | - | - | - | - | - | - | - | - | - | 71.3 | 71.2 |
| 5‴ | - | - | - | - | - | - | - | - | - | 78.0 | 77.9 |
| 6‴ | - | - | - | - | - | - | - | - | - | 62.5 | 62.4 |
| Solvent | CD3OD | CD3OD | CD3OD | DMSO-d6 | DMSO-d6 | DMSO-d6 | CD3OD | DMSO-d6 | CD3OD | CD3OD | CD3OD |
| References | [80] | [82] | [160] | [161] | [162] | [163] | [74] | [164] | [81] | [160] | [160] |