Table 35.
The 13C-NMR spectral data of compounds 149–155.
| C | 149 | 150 | 151 | 152 | 153 | 154 | 155 |
|---|---|---|---|---|---|---|---|
| 2 | 167.4 | 169.5 | 162.7 | 167.6 | 167.6 | 170.9 | 168.7 |
| 3 | 108.7 | 108.0 | 111.1 | 107.5 | 107.4 | 105.6 | 108.6 |
| 4 | 182.7 | 184.2 | 175.3 | 181.9 | 181.8 | 182.5 | 182.6 |
| 5 | 160.0 | 160.9 | 160.7 * | 158.6 | 158.5 | 159.2 | 160.3 |
| 6 | 104.1 | 105.0 | 104.9 | 103.1 | 103.1 | 103.8 | 102.5 |
| 7 | 159.6 | 160.4 | 152.7 * | 163.5 | 163.3 | 164.1 | 164.3 |
| 8 | 94.9 | 95.8 | 91.1 | 109.8 | 109.9 | 110.5 | 105.8 |
| 9 | 156.3 | 157.7 | 157.8 | 152.9 | 152.7 | 153.1 | 155.0 |
| 10 | 104.4 | 105.0 | 107.7 | 105.5 | 105.4 | 106.5 | 106.1 |
| 2′ | 78.4 | 79.3 | 76.6 | 69.6 | 69.6 | 70.2 | 74.2 |
| 3′ | 74.3 | 75.0 | 72.4 | 135.2 | 135.0 | 135.8 | 73.5 |
| 4′ | 22.3 | 22.7 | 22.4 | 124.7 | 124.7 | 125.2 | 132.7 |
| 5′ | - | - | - | 20.6 | 20.3 | 20.9 | 117.3 |
| 1″ | 102.4 | 102.0 | 100.4 | 101.2 | 100.9 | 101.9 | 103.9 |
| 2″ | 74.9 | 74.9 | ** | 72.8 | 72.6 | 73.3 | 73.7 |
| 3″ | 78.4 | 78.1 | 76.9 | 76.8 | 76.1 | 76.8 | 76.5 |
| 4″ | 71.8 | 71.9 | 70.2 | 70.1 | 69.4 | 70.1 | 70.9 |
| 5″ | 78.4 | 75.0 | 76.9 | 76.6 | 75.2 | 76.6 | 76.0 |
| 6″ | 63.0 | 68.8 | 61.3 | 60.6 | 67.7 | 61.6 | 68.5 |
| 1‴ | - | 111.0 | - | - | 102.7 | - | 103.4 |
| 2‴ | - | 77.9 | - | - | 72.8 | - | 73.7 |
| 3‴ | - | 80.5 | - | - | 76.1 | - | 76.9 |
| 4‴ | - | 75.0 | - | - | 69.4 | - | 70.0 |
| 5‴ | - | 65.7 | - | - | 75.9 | - | 77.0 |
| 6‴ | - | - | - | - | 60.4 | - | 61.1 |
| 2a | 20.1 | 20.4 | 19.0 | 19.4 | 19.2 | 59.7 | 20.1 |
| 2’a | 22.3 | 22.4 | 21.2 | - | - | - | - |
| 2’b | 25.7 | 26.1 | 25.2 | - | - | - | - |
| 3’a | - | - | - | 69.6 | 69.6 | 70.2 | 73.0 |
| 7-OCH3 | - | - | 56.0 | - | - | - | - |
| Solvent | CDCl3 | CD3OD | DMSO-d6 | DMSO-d6 | DMSO-d6 | DMSO-d6 | DMSO-d6 |
| References | [121] | [119] | [123] | [108] | [108] | [108] | [109] |
* Interchangeable data. ** The authors missed the assignment of this position.