Table 1.
Type of BNPs | Plant Species: Scientific Name (Family)—Common Name | Salt Concentration | Report Extract: Salt Solution |
Synthesis Temperature | Time (min) |
Size (nm) |
Shape | Ref. |
---|---|---|---|---|---|---|---|---|
Au–Ag BNPs | Solidago canadensis: (Asteraceae)—Canada goldenrod | 1 mM AgNO3
1 mM HAuCl4·3H2O |
1:5:5 | 70–80 °C with stirring |
60 | 25.9 | spherical | [51] |
Geum urbanum L.: (Rosaceae)—Wood avens | 5 mM AgNO3 5 mM HAuCl4 |
1:1:1 | 65 °C with stirring |
720, 1080 and 1440 | 50 | spherical, triangular, hexagonal | [52] | |
Asparagus racemosus: (Asparagaceae)—Shatavari |
1 mM HAuCl4 1 mM AgNO3 |
1:5:5 | irradiation with a frequency of 2.45 GHz and a power of 700 w | 20 | 10–50 | spherical | [53] | |
Moringa oleifera Lam.: (Moringaceae)—Moringa | 1 mM AgNO3 1 mM HAuCl4 |
1:2:3 | 25 °C | 25 | 109 | spherical | [54] | |
Stigmaphyllon ovatum: (Malpighiaceae)—Amazonvine | 1 mM AgNO3 1 mM HAuCl4 |
1:1:1 | 70–80 °C with stirring |
60 | 15 | spherical | [46] | |
Artocarpus heterophyllus: (Moraceae)—Jack tree | 3 mM AgNO3 3 mM HAuCl4 |
1:1:1 | solar heating | - | 15 | spherical | [55] | |
Commelina nudiflora L.: (Commelinaceae)—Carolina dayflower | 1 mM HAuCl4 1 mM AgNO3 |
1:2:2 | 25 °C | 120 | 20–80 | spherical, rod, triangular | [56] | |
Madhuca longifolia: (Sapotaceae)—Madkam | 1 mM HAuCl4 1 mM AgNO3 |
1:10:10 | Ultrasonic liquid processors (20 kHz) |
40 | 34–66 | spherical | [57] | |
Gloriosa superba L.: (Colchicaceae)—Flame lily | 1 mM AgNO3 1 mM HAuCl4·3H2O |
1:10:10 | 25 °C | 10 | 10 | spherical | [15] | |
Pulicaria undulata: (Asteraceae) | 10 mM HAuCl4·3H2O 10 mM AgNO3 |
2:9:1 | 25 °C with stirring |
120 | 5–12 | spherical | [58] | |
Piper pedicellatum: (Piperaceae)—Piper | 1 mM AgNO3 1 mM HAuCl4 |
1:15:15 | 30 °C with stirring |
120 | 3.0–45.0 | spherical | [59] | |
Ag–Pt BNPs | Vernonia mespilifolia: (Asteraceae)—Bitter tea | 1 mM AgNO3
1 mM K2PtCl4 |
1:5:5 | 85 °C with stirring |
60 | 35.5 ± 0.8 | spherical | [60] |
Crocus sativus L.: (Iridaceae)—Saffron crocus | 1 mM AgNO3 1 mM K2PtCl4 |
1:2:2 | 100 °C with stirring |
60 | 36 | spherical | [49] | |
Ag–Pd BNPs | Terminalia chebula: (Combretaceae)—Chebulic myrobalan | 0.01 M PdCl2 0.01 M AgNO3 |
- | 25 °C | 60 | 20–70 | spherical | [47] |
Catharanthus roseus: (Apocynaceae)—Bright eyes | 1 mM AgNO3 1 mM PdCl2 |
1:4:4 | 25 °C | 60 | 15–30 | cubic | [61] | |
Cacumen platyclade: (Cupressaceae)—Chinese Arborvitae Leaf and Twig | 1 mM AgNO3 1 mM PdCl2 |
1:4:4 | 25 °C | 60 | 11.9 ± 0.8 | spherical | [62] | |
1:1:1 | 9.1 ± 0.7 | |||||||
1:1:3 | 7.4 ± 0.4 | |||||||
Lithodora hispidula: (Boraginaceae) | 1 mM AgNO3 1 mM K2PdCl4 |
1:2:2 | 25 °C with stirring |
20 | 15.03–21.60 | spherical | [63] | |
Au–Pd BNPs | Euphorbia condylocarpa: (Euphorbiaceae)—Euphorbia | 0.2 mM HAuCl4 1 mM PdCl2 |
1:1:1 | 50 °C with stirring |
120 | 80 | spherical | [64] |
Cacumen platyclade: (Cupressaceae)—Chinese Arborvitae Leaf and Twig | 0.25 mM HAuCl4 0.25 mM PdCl2 |
1:2:2 | 25 °C with stirring |
120 | 7.4 | spherical | [65] | |
Cacumen platyclade: (Cupressaceae)—Chinese Arborvitae Leaf and Twig | 5 mM HAuCl4 5 mM Na2PdCl4 |
1:4:4 | 25 °C | 30 | 47.8 | flower-like core-shell | [66] | |
Citrus limon L.: (Rutaceae)—Lemon | 1 mM PdCl2 1 mM HAuCl4·3H2O |
1:9:9 | 25 °C | 5 | 2–10 | spherical | [67] | |
Au–Pt BNPs | Asarum europaeum L.:(Aristolochiaceae)—Asarabacca | 1 mM HAuCl4 1 mM K2PtCl6 |
1:1:1 | 80 °C | 1440 | 5–6 | spherical | [68] |
Phragmites australis: (Poaceae)—Common reed | 1 mM HAuCl4 1 mM K2PtCl4 |
1:5:5 | 85 °C | 60 | 35.1 ± 2.71 | flower-like core-shell |
[69] | |
Pt–Pd BNPs | Annona muricata L.: (Annonaceae)—Sirsak | H2PtCl6·6H2O PdCl2, 0.25:0.75, 0.5:0.5, 0.75:0.25 |
1:1:3 1:1:1 1:3:1 |
100 °C with stirring |
120 | 3.97–7.06 | spherical | [70] |
Dioscorea bulbifera L.: (Dioscoreaceae)—Air potato | 1 mM H2PtCl6·6H2O 1 mM PdCl2 |
1:1:1 | 100 °C | 300 | 20–25 | irregular shape | [71] | |
Cu–Ag BNPs | Kigelia Africana: (Bignoniaceae)—Sausage tree | 1 mM CuCl2·H2O, 1 mM AgNO3 | 1:1:2 | 120 °C | 60–360 | 10 | spherical | [72] |
Rheum emodi: (Polygonaceae)—Rhubarb | 10 mM AgNO3 10 mM Cu(CH3COO)2 |
5:2:15 | 90 °C with stirring |
180 | 40–50 | spherical | [73] | |
ZnO–Ag BNPs | Mirabilis jalapa: (Nyctaginaceae)—Marvel of Peru | Zn(O2CCH3)2 (H2O)2 AgNO3 0.5:0.5, 0.1:0.1, 0.5:0.1, 0.1:0.5 and 1:1 mM |
1:1:1 | 60 ± 5 °C | 120 | 19.3–67.4 | spherical | [74] |
Ag–Ni BNPs | Senna occidentalis: (Fabaceae)—Coffee senna | AgNO3 Ni(NO3)2·6H2O 1 mM:1 mM 1 mM:2 mM 2 mM:2 mM |
1:5:5 1:5:10 1:10:10 |
700 °C with stirring |
10 | 10.25 ± 4.19 | pseudo-cubic | [75] |