Table 2.
Selected bond lengths and bond angles of complex 1.
| Moiety | Bond Length, Å | Moiety | Bond length, Å |
|---|---|---|---|
| Cu1—O2 | 1.9647 (18) | O1—C8 | 1.250 (3) |
| Cu1—O4 | 1.9725 (17) | O2—C8i | 1.250 (3) |
| Cu1—O1 | 1.9780 (16) | O3—C16 | 1.248 (3) |
| Cu1—O3 | 1.9785 (17) | O4—C16i | 1.252 (3) |
| Cu1—N1 | 2.2009 (17) | N1—C21 | 1.329 (3) |
| Cu1—Cu1i | 2.6917 (8) | N1—C17 | 1.340 (3) |
| Moiety | Bond Angle, ° | Moiety | Bond Angle, ° |
| O2—Cu1—O4 | 89.12 (9) | O3—Cu1—Cu1i | 85.30 (5) |
| O2—Cu1—O1 | 166.33 (6) | N1—Cu1—Cu1i | 172.81 (5) |
| O4—Cu1—O1 | 89.25 (8) | C8—O1—Cu1 | 124.15 (14) |
| O2—Cu1—O3 | 89.05 (8) | C8i—O2—Cu1 | 123.48 (14) |
| O4—Cu1—O3 | 166.47 (6) | C16—O3—Cu1 | 121.16 (14) |
| O1—Cu1—O3 | 89.37 (8) | C16i—O4—Cu1 | 126.36 (15) |
| O2—Cu1—N1 | 101.95 (7) | C21—N1—C17 | 118.2 (2) |
| O4—Cu1—N1 | 94.42 (7) | C21—N1—Cu1 | 127.34 (17) |
| O1—Cu1—N1 | 91.71 (7) | C17—N1—Cu1 | 114.02 (16) |
| O3—Cu1—N1 | 99.07 (7) | O2i—C8—O1 | 125.5 (2) |
| O2—Cu1—Cu1i | 83.75 (6) | O2i—C8—C7 | 115.36 (19) |
| O4—Cu1—Cu1i | 81.18 (5) | O1—C8—C7 | 119.1 (2) |
| O1—Cu1—Cu1i | 82.59 (6) | ||
Symmetry code: (i) −x + 1, −y + 1, −z + 1.