Table 3.
Selected bond lengths and bond angles of complex 2.
| Moiety | Bond Length, Å | Moiety | Bond length, Å |
|---|---|---|---|
| Cu1—N1i | 1.972 (3) | Cu2—O2 | 2.153 (2) |
| Cu1—N1 | 1.972 (3) | Cu2—Cu2ii | 2.6586 (9) |
| Cu1—O1 | 1.979 (2) | C8—F1 | 1.337 (5) |
| Cu1—O1i | 1.979 (2) | F3—C16 | 1.358 (5) |
| Cu2—O3 | 1.957 (3) | F4—C24 | 1.357 (4) |
| Cu2—O5 | 1.960 (3) | N1—C25 | 1.344 (5) |
| Cu2—O4ii | 1.962 (3) | N1—C29 | 1.348 (5) |
| Cu2—O6ii | 1.974 (2) | O1—C1 | 1.269 (3) |
| O4—C9 | 1.253 (4) | O2—C1 | 1.248 (4) |
| O5—C17 | 1.251 (4) | O3—C9 | 1.247 (4) |
| O6—C17 | 1.243 (4) | ||
| Moiety | Bond Angle, ° | Moiety | Bond Angle, ° |
| N1i—Cu1—N1 | 180.0 | C1—O1—Cu1 | 112.85 (19) |
| N1i—Cu1—O1 | 89.89 (11) | C1—O2—Cu2 | 129.7 (2) |
| N1—Cu1—O1 | 90.11 (11) | C9—O3—Cu2 | 123.2 (2) |
| N1i—Cu1—O1i | 90.11 (11) | C9—O4—Cu2ii | 123.2 (2) |
| N1—Cu1—O1i | 89.89 (11) | C17—O5—Cu2 | 122.0 (2) |
| O1—Cu1—O1i | 180.0 | C17—O6—Cu2ii | 124.1 (2) |
| O3—Cu2—O5 | 89.18 (14) | O2—C1—O1 | 122.7 (3) |
| O3—Cu2—O4ii | 167.32 (10) | O2—C1—C2 | 118.6 (3) |
| O5—Cu2—O4ii | 88.89 (13) | O1—C1—C2 | 118.6 (3) |
| O3—Cu2—O6ii | 90.88 (12) | O3—C9—O4 | 125.9 (3) |
| O5—Cu2—O6ii | 167.28 (10) | O3—C9—C10 | 118.3 (3) |
| O4ii—Cu2—O6ii | 88.27 (11) | O3—Cu2—Cu2ii | 83.86 (8) |
| O3—Cu2—O2 | 92.74 (10) | O5—Cu2—Cu2ii | 84.78 (8) |
| O5—Cu2—O2 | 95.68 (10) | O4ii—Cu2—Cu2ii | 83.49 (8) |
| O4ii—Cu2—O2 | 99.92 (10) | O6ii—Cu2—Cu2ii | 82.58 (7) |
| O6ii—Cu2—O2 | 97.03 (9) | O2—Cu2—Cu2ii | 176.56 (7) |
Symmetry codes: (i) −x + 1, −y + 2, −z + 1; (ii) −x + 1, −y + 1, −z + 1.