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. 2021 Dec 15;6(51):35355–35362. doi: 10.1021/acsomega.1c04606

Table 7. Controllability Indices and Desirability and Values for the Systems.

  extractive distillation pressure swing distillation
purity of THF 95 mol % 99.9 mol % 95 mol % 99.9 mol %
control structure R1-R2-Q2 L1-L2-Q2 R1-R2-Q2 L1-L2-Q2 R1-R2 Q1-Q2 R1-R2 Q1-Q2
time constant (h) 0.41 h 0.41 h 0.45 h 0.45 h 0.13 h 0.13 h 0.3 h 0.3 h
frequency (rad/s) 6.68 × 10–4 6.68 × 10–4 6.68 × 10–4 6.68 × 10–4 2.14 × 10–3 2.14 × 10–3 9.26 × 10–4 9.26 × 10–4
MRI 4.73 × 10–3 5.17 × 10–3 1.44 × 10–3 1.41 × 10–3 5.44 × 10–3 1.44 × 10–1 1.72 × 10–4 5.01 × 10–3
CN 5.17 × 103 3.51 × 103 5.00 × 103 3.42 × 103 1.43 × 101 3.19 × 100 2.47 × 102 5.01 × 101
RGAno 3.74 × 102 2.59 × 102 6.01 × 102 4.13 × 102 9.69 × 100 9.81 × 10–1 7.10 × 101 1.59 × 101
dMRI 4.62 × 10–2 5.04 × 10–2 1.43 × 10–2 1.40 × 10–2 5.30 × 10–2 7.62 × 10–1 1.72 × 10–3 4.89 × 102
dCN 1.96 × 10–16 2.19 × 10–11 6.21 × 10–16 4.09 × 10–11 9.04 × 10–1 9.78 × 10–1 1.78 × 10–1 7.04 × 10–1
dRGAno 5.50 × 10–17 5.70 × 10–12 8.08 × 10–27 1.13 × 10–18 3.79 × 10–1 9.07 × 10–1 8.26 × 10–4 2.05 × 10–1
aggregated desirability 7.92 × 10–12 1.85 × 10–8 4.16 × 10–15 8.66 × 10–11 2.63 × 10–1 8.77 × 10–1 6.32 × 10–3 1.92 × 10–1