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. 2021 Dec 14;143(51):21594–21603. doi: 10.1021/jacs.1c09573

Table 2. Substrate Scope.

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a

Reaction conditions: 0.15 mmol of substrate, 1 mol % catalyst, and 1.5 mL of DCM. Conversion was determined by 1H NMR spectroscopy. Enantiomeric excess was determined by SFC or GC analysis using chiral stationary phases.

b

Class 2 optimized conditions: H2 (1 bar) at 60 °C in 1 mL of DCE.

c

A 9:1 E/Z mixture was employed.