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. Author manuscript; available in PMC: 2022 Jan 3.
Published in final edited form as: Acc Chem Res. 2021 Nov 30;54(24):4545–4564. doi: 10.1021/acs.accounts.1c00573

Table 1.

Ligand Effects in Co-Catalyzed HV of 1,3-Dienes

graphic file with name nihms-1767554-t0015.jpg
no. ligand T (°C) (4,1)-Z (4,1)-E (2,1)-E
1. DPPB −20 94 <1 0
2. DPPP a −20 75 0 0
3. DPPP 23 0 26 65
4. DPPM −20 <2 33 64
a

+ 14% 1,4-linear.