Table 3. Mulliken population analysis for unoccupied MOs of the UO₂(S₂PR ₂)₂(EtOH).

Compound	MO		Energy (eV)	% S 3p	% S 3p average
UO2(S2PPh2)2(EtOH)	5f	1a	−2.96	2.68	2.86
		2a	−2.93	3.75
		3a	−2.91	1.95
		4a	−2.90	3.04
	6d	5a	0.32	12.11	13.15
		6a	0.67	9.00
		7a	0.73	13.43
		8a	1.73	14.43
		9a	1.86	16.78
	{\rm{C}}_\pi^{\,\ast}	10a	−1.34	9.25	2.25
		11a	−0.80	0.39
		12a	−0.77	0.62
		13a	−0.59	0.51
		14a	−0.56	0.50
UO2[S2P(o-CF3C6H4)2]2(EtOH)	5f	1a	−3.30	1.95	2.81
		2a	−3.27	4.09
		3a	−3.25	2.48
		4a	−3.24	2.73
	6d	5a	−0.80	13.00	12.71
		6a	−0.35	21.93
		7a	0.50	8.94
		8a	1.45	6.29
		9a	1.51	13.39
	{\rm{C}}_\pi^{\,\ast}	10a	−1.88	6.95	3.65
		11a	−1.85	4.78
		12a	−1.80	6.15
		13a	−1.74	5.48
		14a	−1.27	0.73
		15a	−1.26	0.80
		16a	−1.18	2.77
		17a	−1.16	1.54