| k | Hydraulic permeability (m/s) |
| kr | Relative hydraulic conductivity |
| Proposed relative hydraulic conductivity of compacted bentonite | |
| ksat | The saturated hydraulic conductivity (m/s) |
| kunsat | The unsaturated hydraulic conductivity (m/s) |
| Se | The effective saturation |
| θ | The actual volumetric water content |
| θr | The residual volumetric water content |
| θs | The saturated volumetric water content |
| α | The constant parameter in Mualem [54] |
| μ | A dimensionless number in Burdine [31] |
| Ψ | Suction of soil/bentonite(MPa) |
| Ψd | The air entry value (MPa) |
| λ | A fitting factor related to pore-size distribution |
| Cs | Shape factor |
| τ | Tortuosity |
| γw | Unit weight of water (N/m3) |
| η | Viscosity of water (Pa∙s) |
| SA | Specific surface area (m2/kg) |
| Φ | Porosity |
| ρd | Dry density of soil (kg/m3) |
| Atot | Total specific surface area (m2/kg) |
| n | The number of TOT layers of per particle |
| N | Total number of TOT layers of bentonite sample |
| Aext | External specific surface area of bentonite (m2/g) |
| As | The surface area of a single TOT layer |
| msi | Mass of one particle (kg) |
| msmectite | Mass of smectite (kg) |
| ms | Mass of solid (kg) |
|
b
C |
A constant related to water adsorption rate A correction term |
| ω | Water content (kg/kg) |
| ρw | Density of water (kg/m3) |
| mw | The mass of water (kg) |
| Vt | Total volume of soil sample (m3) |
| Vw | Volume of total water in soil (m3) |
| Dry density of smectite (kg/m3) | |
| dTOT | Thickness of TOT layer (9.5 Å) |
| dt | Basal spacing (Å) |
| hw | Total interlayer water thickness of soil |
| Vimw | Micro pore volume/volume of interlayer water |
| Ve | Macro pore volume/effect pore volume |
| Vs | Volume of solid (m3) |
| diw | Interlayer water thickness between two TOT layers |
| Φmacro | Macro porosity (Effective porosity) |
| Φmicro | Micro porosity (Interlayer porosity) |
| ρs | Density of the solid (kg/m3) |
| ρi | Density of the non-smectite minerals or impurities (kg/m3) |
| Gs | Specific gravity of clay |
| Xsm | The mass fraction of smectite in the bentonite |
| Le | Effective path length of flow |
| L | Sample length |
| ref | The reference case in which measurements are available |
| β | A fitting factor between Φ and Ψ in Pham et al. [92] |
| σ | Coefficient related to porosity and size of pore |
| Xhs | Mole fraction of hydrated smectite |
| Msm | Molar mass of dry smectite (Kg/mol) |
| ζc | The number of moles of waters in the interlayer adsorption or desorption reaction |
| υil | The molar volume of the interlayer water (m3/mol) |
| a, m | Curve-fitting parameters by van Genuchten [24] |
| nmax, nmin | The maximum and minimum number of TOT layers of bentonite particle respectively |