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. 2022 Jan 10;13:39. doi: 10.1038/s41467-021-27804-5

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© The Author(s) 2022

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 2 — All reactions were carried out under the standardized conditions: 4 mM of substrate was incubated with 1 mol% of ruthenium catalyst 1 in PBS/1,4-dioxane (9:1) for 2 h at 37 °C. TON values were determined from product yields obtained by HPLC analysis; where TON_Arom refers to final product and TON_RCM refers to the combination of cyclohexadien-1-ol intermediate/final product. TON_RCM for compound 11 was calculated based on starting material conversion. Reactions were performed in triplicate.